An ultra-stable prelithiated Sn anode for sulfide-based all-solid-state Li batteries.

Chem Commun (Camb)

The Soft2D Lab, State Key Laboratory of Metal Matrix Composites, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.

Published: March 2025

A prelithiated Sn (LiSn) anode was developed for sulfide-based all-solid-state Li batteries (ASSLBs), demonstrating high compatibility with LiPSCl sulfide electrolyte. The LiSn|NCM811 cell achieved 163 mA h g capacity (0.1C) and 91% retention after 650 cycles (1C). Prelithiation compensated Li loss and mitigated volume expansion, enabling high-performance ASSLBs.

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http://dx.doi.org/10.1039/d5cc00685fDOI Listing

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