In this work, we investigated the response of the metal-organic framework MIL-125-NH to ball-milling. Both localised and bulk analyses revealed prolongued ball-milling results in a complete loss of long-range structural order. Investigation of this disorder revealed partial retention of the local bonding of the secondary building unit, suggesting structure collapse progressed primarily through metal-linker bond breakage. We explored the photocatalytic performance of the materials, and examined the materials' band gap using UV-Vis reflectance spectroscopy.
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| http://dx.doi.org/10.1039/d4cc06320a | DOI Listing |
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