Multicolor dynamic optical materials exhibit significant potential in the realms of anticounterfeiting and information encryption, benefitting from their capacity for generating unpredictable optical information that changes over time. Herein, a novel approach is presented utilizing quantum-confinement effect of MAPbBr quantum dots (QDs) embedded within lanthanide-metal organic frameworks (Ln-MOFs) for time-resolved multicolor dynamic anticounterfeiting applications. The dimensions of MAPbBr QDs undergo temporal variations during in situ growth, resulting in dynamic alterations in luminescent color due to the quantum-confinement effect. Furthermore, the emission colors of MAPbBr@Eu-MOFs can be modulated by varying UV excitation wavelengths, thereby conferring a spatially distinguishable anticounterfeiting dimension. The time-resolved unpredictability of these dynamic color changes coupled with sustained luminescent intensity and multi-dimensional anticounterfeiting, render them suitable system for advanced graphical coding. These findings pave the way for the advancement of intelligent multicolor dynamic optical anticounterfeiting.
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http://dx.doi.org/10.1002/adma.202501271 | DOI Listing |
ACS Nano
March 2025
State Key Laboratory of Bioinspired Interfacial Materials Science, Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191, P. R. China.
Micropatterning quantum dots (QDs) is a key process for making high-performance quantum dot light-emitting diodes (QLEDs), which have shown advantages in lighting and displays. So far, various solution processes have been developed for fabricating micropatterned QDs, where both uniform distribution and well-defined edges are desirable. Very recently, with the flourishing of near-eye displays, high-resolution QD micropatterns appear particularly attractive, which regretfully have progressed poorly due to the extremely complicated liquid dynamics at microscale.
View Article and Find Full Text PDFAdv Mater
March 2025
Key Laboratory of Photochemistry, Institute of Chemistry Chinese Academy of Sciences, Beijing, 100190, China.
Multicolor dynamic optical materials exhibit significant potential in the realms of anticounterfeiting and information encryption, benefitting from their capacity for generating unpredictable optical information that changes over time. Herein, a novel approach is presented utilizing quantum-confinement effect of MAPbBr quantum dots (QDs) embedded within lanthanide-metal organic frameworks (Ln-MOFs) for time-resolved multicolor dynamic anticounterfeiting applications. The dimensions of MAPbBr QDs undergo temporal variations during in situ growth, resulting in dynamic alterations in luminescent color due to the quantum-confinement effect.
View Article and Find Full Text PDFAnal Chem
March 2025
College of Physics and Optoelectronic Engineering, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, State Key Laboratory of Radio Frequency Heterogeneous Integration (Shenzhen University), Shenzhen University, Shenzhen, Guangdong 518060, China.
Fluorescence imaging is a key tool for visualizing the morphology and dynamics of nucleic acids (DNA and RNA) in living cells to understand their role in regulating the growth, development, and reproduction of organisms. However, effective probes capable of simultaneously targeting both DNA and RNA, as well as tools for analyzing their distribution and relative ratios in organisms, are currently lacking. Therefore, fluorine-nitrogen codoped carbon dots with two-photon absorption (F-NCDs) were synthesized by the hydrothermal method and exhibited stable fluorescence, good biocompatibility, and a fluorescence lifetime sensitive to nucleic acids (DNA and RNA).
View Article and Find Full Text PDFChem Bio Eng
March 2024
School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, China.
Conventional room temperature phosphorescence (RTP) polymer materials lack a dynamic structural change mechanism for on-demand phosphorescence emission, limiting their application in specific scenarios, such as smart devices. However, the development of RTP polymer materials with an on-demand emission capability is highly attractive yet rather challenging. Herein, we report a novel RTP polymer material that doped purely organic chromophores into a polymer network with numerous free hydroxyl side chains.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2025
Department of Electrical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-Ro Nam-Gu, Pohang, Gyeongbuk 37673, Republic of Korea.
With the rapid advancement of modern communication technologies, safeguarding information against forgery and unauthorized access has become increasingly critical, driving interest in advanced optical encryption systems. These systems excel in parallel image data processing, enabling swift detection and verification of sensitive information. However, traditional light-based encoding methods are constrained by their limited dependence on static parameters such as light wavelength and intensity and lack dynamic, reversible adaptability.
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