Coastal regions, as hotspots for non-methane hydrocarbons (NMHCs) emissions, warrant more consideration for their vital impacts on marine climate regulation. This study examined the spatiotemporal distributions, emissions, and environmental effects of NMHCs in the Bohai Sea (BS) and Yellow Sea (YS) during summer and winter. The NMHC concentrations show clear spatial and seasonal variability, with higher levels observed in summer. The horizontal distributions of isoprene closely mirrored chlorophyll-a (Chl-a), suggesting a strong linkage to phytoplankton activities, while other NMHCs appeared to be associated with photochemical processes. Atmospheric alkane concentrations declined from inshore regions to offshore regions indicating the significant input of terrestrial sources, whereas alkenes were predominantly emitted from the ocean. The NMHC sea-to-air fluxes ranged from 11.8 to 306 nmol m d, underscoring the importance of coastal regions as major sources of atmospheric NMHCs. These emissions significantly promote the formation of secondary organic aerosol (SOA) and ozone (O), thereby exerting a vital impact on the marine environment.
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http://dx.doi.org/10.1016/j.marenvres.2025.107059 | DOI Listing |
Mar Environ Res
March 2025
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao, 266100, China; Laoshan Laboratory, Qingdao, 266237, China; College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, China.
Coastal regions, as hotspots for non-methane hydrocarbons (NMHCs) emissions, warrant more consideration for their vital impacts on marine climate regulation. This study examined the spatiotemporal distributions, emissions, and environmental effects of NMHCs in the Bohai Sea (BS) and Yellow Sea (YS) during summer and winter. The NMHC concentrations show clear spatial and seasonal variability, with higher levels observed in summer.
View Article and Find Full Text PDFNat Commun
February 2025
Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), 04318, Leipzig, Germany.
Isoprene (CH) globally accounts for half of the non-methane hydrocarbon flux into Earth´s atmosphere. Its degradation is mainly initiated by the gas-phase reaction with OH radicals yielding a complex system of RO radicals. Subsequent product formation is not conclusively understood yet.
View Article and Find Full Text PDFEnviron Pollut
January 2025
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China; School of Resources and Environment, University of Chinese Academy of Sciences, Beijing, China.
The emission factors and characteristics of pollutants from river vessels are critical for understanding the environmental impact of ship emissions, particularly in inland waterways. However, research gaps remain regarding emissions of volatile organic compounds (VOCs) and intermediate-volatility organic compounds (IVOCs) from river vessels. In this study, we collected and analyzed organic vapor emissions, including non-methane hydrocarbon (NMHCs), oxygenated volatile organic compounds (OVOCs) and IVOCs, from three river vessels under different operating conditions.
View Article and Find Full Text PDFWaste Manag
December 2024
Department of Earth and Atmospheric Sciences, GEOTOP/UQAM, Montreal, Canada.
Nat Commun
September 2024
Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China.
Ethane is the most abundant non-methane hydrocarbon in the troposphere, where it impacts ozone and reactive nitrogen and is a key tracer used for partitioning emitted methane between anthropogenic and natural sources. However, quantification has been challenged by sparse observations. Here, we present a satellite-based measurement of tropospheric ethane and demonstrate its utility for fossil-fuel source quantification.
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