In 1939 London and Bauer published a 'little book' that shaped the debate over the role of consciousness in resolving the measurement problem in quantum mechanics. Mistakenly understood as merely summarising von Neumann's account, both sides in the debate failed to appreciate its phenomenological underpinnings. London not only originally studied phenomenology but continued thinking about and discussing this approach in the years leading up to the publication of his work with Bauer, most notably with Gurwitsch, who likewise had a dual background in phenomenological philosophy and physics. In the book, A Phenomenological Approach to Quantum Mechanics: Cutting the Chain of Correlations (French, 2023), the historical background to London and Bauer's work is set out prior to situating it within the context of Husserl's philosophy as a whole. It is concluded that the London and Bauer phenomenological account offers a potentially fruitful way forward through various dichotomies, such as that between psi-ontic and psi-epistemic accounts and between interpretational and reconstructive approaches more generally, as well as with regard to understanding quantum physics more generally. In this paper London and Bauer's insistence that quantum mechanics should be seen as a theory of knowledge in its own right is emphasized, where this must be taken as phenomenologically grounded. Hopefully this work will be viewed as contributing to a revised phenomenological understanding of modern physics, standing alongside Ryckman's The Reign of Relativity (Ryckman, 2005) and Berghofer and Wiltsche's edited collection Phenomenological Approaches to Physics (Berghofer & Wiltsche, 2020).
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http://dx.doi.org/10.1016/j.shpsa.2025.02.001 | DOI Listing |
Nanomaterials (Basel)
March 2025
The George S. Wise Faculty of Life Sciences, Tel Aviv University, Tel Aviv 6997801, Israel.
Here, we demonstrate through AFM imaging and CD spectroscopy that the binding of silver ions (Ag) to poly(dGdC), a double-stranded (ds) DNA composed of two identical repeating strands, at a stoichiometry of one Ag per GC base pair induces a one-base shift of one strand relative to the other. This results in a ds nucleic acid-Ag conjugate consisting of alternating CC and GG base pairs coordinated by silver ions. The proposed organization of the conjugate is supported by the results of our Quantum Mechanical (QM) and Molecular Mechanics (MMs) calculations.
View Article and Find Full Text PDFNatl Sci Rev
March 2025
Lebanese University, Faculty of Sciences II, Department of Natural Sciences, Jdeideh, Matn, Lebanon.
With the exception of a fly and a mite from the Triassic of Italy, all Mesozoic amber arthropods are from the Cretaceous. Late Jurassic Lebanese amber from Aintourine revealed a completely preserved adult coccid male (wing length 0.8 mm), gen.
View Article and Find Full Text PDFJ Phys Chem B
March 2025
Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Saga 840-8502, Japan.
Cyanobacteriochromes (CBCRs) are phytochrome-related photosensors that utilize a linear tetrapyrrole (bilin) as a chromophore. Cyanobacteriochrome RcaE belongs to the green/red-type subfamily that photoconverts between green-absorbing (Pg) and red-absorbing (Pr) states. This subfamily shows a protochromic photocycle, leveraging a protonation state change at the B ring pyrrole nitrogen (N) to induce a large absorption shift.
View Article and Find Full Text PDFDalton Trans
March 2025
Department of Chemistry, University of Kurdistan, Sanandaj 66177-15175, Iran.
The catalytic activity of the binuclear glyoxalase II (GlxII) enzyme is closely linked to the type and charge of metal ions in its active site. Using hybrid quantum mechanics/molecular mechanics (QM/MM) calculations, we investigated the reaction mechanism of human GlxII, which features two Zn(II) ions in its active site. By systematically replacing these Zn(II) ions with Fe(II), Fe(III), or Co(II), we evaluated the impact of metal substitutions on reaction energetics and active-site geometry.
View Article and Find Full Text PDFJ Phys Chem Lett
March 2025
Institute of Theoretical and Computational Chemistry, Faculty of Mathematics and Natural Sciences, Heinrich Heine University Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany.
A hybrid quantum mechanics/molecular mechanics setup was used to model the singlet fission (SF) of electronically excited 6,13-bis(triisopropylsilylethynyl)pentacene (TIPS-pentacene) in the crystalline phase. The optically bright S state possesses nearly identical excitation energies and oscillator strengths in the two nonequivalent dimer units with and structural overlap, respectively. A shearing/tilting motion of the two slip-stacked TIPS-pentacene building blocks is the key for stabilizing the singlet-coupled triplet-pair state, (TT), in the overlap situation.
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