This study highlights the effectiveness of hydrodeoxygenation (HDO) in converting lignin oils from Eucalyptus, Poplar, and Pine wood, derived from reductive catalytic fractionation (RCF), into renewable cycloalkanes for jet fuel. Using a low-cost Ni2P/SiO2 catalyst, the process achieved yields of 91 %, 83 %, and 75 % of renewable cycloalkanes respectively. In addition, the process exhibited high selectivity towards a specific range of hydrocarbons mostly present in aviation fuel (C9 to C15), with values of 70%, 60% and 62% for the three feedstocks, respectively, showcasing the potential for high-value fuel production. The research underscores the importance of modifying lignin oil properties through various chemo-catalytic biorefining pathways, which significantly influence the quality of the produced blend via HDO. These findings provide valuable insights into optimizing feedstock characteristics for improved jet-range hydrocarbon production.
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http://dx.doi.org/10.1002/cssc.202402531 | DOI Listing |
Adv Sci (Weinh)
March 2025
Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, State Key Laboratory of Utilization of Woody Oil Resource, Northeast Forestry University, Harbin, 150040, P. R. China.
Catalytic refining of lignin holds promise for producing sustainable platform chemicals. In this work, a gaseous hydrogen-free catalytic hydrodeoxygenation system is developed for upgrading lignin-derived phenols to alkane chemicals. Commercially available Raney Ni and HZSM-5 are used as a combinational catalyst, with isopropanol serving as the hydrogen-donating solvent.
View Article and Find Full Text PDFChemSusChem
March 2025
KU Leuven: Katholieke Universiteit Leuven, Department of Microbial and Molecular Systems, Celestijnenlaan 200f, 3001, Heverlee, BELGIUM.
This study highlights the effectiveness of hydrodeoxygenation (HDO) in converting lignin oils from Eucalyptus, Poplar, and Pine wood, derived from reductive catalytic fractionation (RCF), into renewable cycloalkanes for jet fuel. Using a low-cost Ni2P/SiO2 catalyst, the process achieved yields of 91 %, 83 %, and 75 % of renewable cycloalkanes respectively. In addition, the process exhibited high selectivity towards a specific range of hydrocarbons mostly present in aviation fuel (C9 to C15), with values of 70%, 60% and 62% for the three feedstocks, respectively, showcasing the potential for high-value fuel production.
View Article and Find Full Text PDFACS Sustain Chem Eng
March 2025
Laboratory of Inorganic Materials and Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, Eindhoven 5600 MB, Netherlands.
With the rising demand for fuel and the societal shift toward sustainable resources, lignin emerges as a prime feedstock. Lignin is mainly composed of aromatic compounds linked within a complex matrix and holds significant potential as a source of renewable aromatics. Technical lignin, the most abundant form of lignin, is often degraded due to harsh biomass pretreatment processes.
View Article and Find Full Text PDFPlant J
March 2025
Agronomy Department, Plant Molecular and Cellular Biology Program, Genetics Institute, University of Florida, IFAS, Gainesville, Florida, USA.
Sugarcane, which provides 80% of global table sugar and 40% of biofuel, presents unique breeding challenges due to its highly polyploid, heterozygous, and frequently aneuploid genome. Significant progress has been made in developing genetic resources, including the recently completed reference genome of the sugarcane cultivar R570 and pan-genomic resources from sorghum, a closely related diploid species. Biotechnological approaches including RNA interference (RNAi), overexpression of transgenes, and gene editing technologies offer promising avenues for accelerating sugarcane improvement.
View Article and Find Full Text PDFPlant Biotechnol J
March 2025
Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture, Oil Crops Research Institute of the Chinese Academy of Agricultural Sciences (CAAS), Wuhan, China.
Brassica napus L. (B. napus) is a major edible oil crop grown around the southern part of China, which often faces cold stress, posing potential damage to vegetative tissues.
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