The northern Songliao Basin is shale-oil-rich with high exploration potential. However, its heterogeneity challenge reservoir characterization and evaluation, impeding exploration and development efforts. Thus, analyzing continental shale's pore structure and heterogeneity is crucial. This work utilizes High-pressure mercury intrusion (HMIP) and low-pressure N adsorption (LPNA) methods to analyze the multifractal characteristics of shale pore structures at different depths. Results indicate that there is no significant correlation between the pore structures determined by the two methods. However, the heterogeneity of the pore structure obtained by the HMIP method is stronger than that by the LPNA method. The study also found that as the total pore volume increases, the heterogeneity of the pore structure increases, while the pore connectivity is not significantly correlated with the pore volume. In addition, mineral content has a significant impact on the heterogeneity of pore structure and pore size distribution, especially the content of quartz.
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http://dx.doi.org/10.1038/s41598-025-93078-2 | DOI Listing |
Adv Mater
March 2025
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China.
Adsorbed natural gas (ANG) storage is emerging as a promising alternative to traditional compressed and liquefied storage methods. However, its onboard application is restricted by low volumetric methane storage capacity. Flexible porous adsorbents offer a potential solution, as their dense structures and unique gate-opening effects are well-suited to enhance volumetric capacity under high pressures.
View Article and Find Full Text PDFChem Rec
March 2025
College of Chemistry & Chemical Engineering, Qingdao University, Qingdao, 266071, China.
Biomolecule-engineered metal-organic frameworks (Bio-MOFs) are designed by incorporating biomolecules into or onto MOFs through covalent and non-covalent interactions. These composite frameworks exhibit unique catalytic and biological activities, making them highly suitable for various biocatalytic applications. In this review, we highlight recent advances in the material design, bioengineering methods, structural and functional regulation techniques, and biocatalytic applications of Bio-MOFs.
View Article and Find Full Text PDFNanomaterials (Basel)
March 2025
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China.
Preparing carbon aerogel in an eco-friendly and inexpensive manner remains a significant challenge. The carbon aerogels derived from food waste (FWCAs) with a three-dimensional connected network structure are successfully synthesized using microwave radiation. The as-prepared FWCA-4 (The KOH/C ratio is 4) has a large specific surface area (1470 m/g), pore volume (0.
View Article and Find Full Text PDFNanomaterials (Basel)
February 2025
Zhongyuan Critical Metal Laboratory, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China.
The excessive utilization and emission of waste plastics have caused serious damage to the environment, and it is of great significance to explore high-value utilization methods for these waste plastics. To address this challenge, functional nano cobalt-loaded porous carbon materials (CoPC) with excellent antibiotic wastewater removal properties were prepared by one-step pyrolysis using waste PET plastics as a carbon source, a process described in this paper. Characterization revealed that the obtained CoPC-2 catalysts had a high degree of defects, a large specific surface area (343.
View Article and Find Full Text PDFNanomaterials (Basel)
February 2025
College of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China.
With the advancement of industrial production and urban modernization, pollution from heavy metal ions and the accumulation of solid waste have become critical global environmental challenges. Establishing an effective recycling system for solid waste and removing heavy metals from wastewater is essential. Coal gangue was used in this study as the primary material for the synthesis of a fully coal gangue-based phosphorus-silicon-aluminum (SAPO-5) molecular sieve through a hydrothermal process.
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