High-entropy materials (HEMs) constitute an innovative category of advanced materials distinguished by their distinctive atomic arrangements and remarkable multifunctional attributes. This thorough overview critically analyzes the core principles, synthesis methods, and novel applications of HEMs, emphasizing their transformative potentials in electromagnetic and biological fields. This study examines how the high configurational entropy effect, lattice distortion, and slow diffusion mechanisms facilitate the stabilization of single-phase systems including numerous primary elements. Recent advancements in HEM development have demonstrated exceptional skills in electromagnetic wave absorption, attaining reflection losses of up to - 35.10 dB via nano-domain designs and synergistic dielectric-magnetic loss mechanisms. Including rare-earth elements has substantially affected magnetic ordering and transition temperatures, with La-based compounds displaying spontaneous magnetization of approximately 15.2 emu/g. In biomedical applications, innovative HEM formulations have attained improved biocompatibility with a diminished Young's modulus (69-140 GPa) and exceptional corrosion resistance. This review provides a detailed roadmap for researchers and engineers focused on the practical application of advanced materials, through a methodical analysis of current developments in energy storage, catalysis, electromagnetic shielding, and biological applications. We emphasize the significance of composition design and processing parameters in attaining customized features for specific technological applications while recognizing key difficulties and future research avenues in this swiftly advancing sector.
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http://dx.doi.org/10.1007/s42114-025-01275-4 | DOI Listing |
Nat Commun
March 2025
State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, China.
The recycling of spent lithium-ion batteries can effectively mitigate the environmental and resource challenges arising from the escalating generation of battery waste and the soaring demand for battery metals. The existing mixing-then-separating recycling process is confronted with high entropy-increasing procedures, including crushing and leaching, which result in irreversible entropy production due to the decrease in material orderliness or heavy chemical consumption, thereby hindering its thermodynamic efficiency and economic viability of the entire recycling process. Herein, we propose a galvanic leaching strategy that leverages the self-assembly of LiNiCoMnO particles with their inherent aluminium foil current collectors in spent lithium-ion batteries, creating a primary cell system capable of recovering battery metals without pre-crushing or additional reductants.
View Article and Find Full Text PDFRSC Adv
March 2025
Hubei Longzhong Laboratory Xiangyang 441000 Hubei China.
This study investigates the mechanical responses and deformation mechanisms of CoCrFeMnNi high-entropy alloy (HEA) with varying grain size gradients through molecular dynamics simulations, and explores the tension-compression asymmetry of gradient nanograined high-entropy alloy (G-HEA) under different loading conditions. In the early stage of plastic deformation, the normal stress and shear strain of G-HEA both exhibit gradient distribution characteristics under compression and tension. However, as the engineering strain increased, these gradient distribution characteristics gradually diminished and ultimately disappeared.
View Article and Find Full Text PDFNano Lett
March 2025
Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853, United States.
High-entropy semiconducting nanocrystals involving the random incorporation of five or more metals within a single, disordered lattice are receiving significant research interest as catalytic materials. Among these, high-entropy sulfide (HES) nanocrystals demonstrate potential as electrocatalysts but have been slower to gain research interest compared to other high-entropy systems due to the complications introduced by multistep, high-temperature synthesis techniques and the issues of material stability during performance. In this work, we report a simple, reproducible, and scalable HES synthesis to produce star-like nanocrystals.
View Article and Find Full Text PDFACS Omega
March 2025
College of Materials Science & Engineering, Yingkou Institute of Technology, Yingkou 115000, China.
A series of CrFeNiAlSiB ( = 0.1, 0.3, 0.
View Article and Find Full Text PDFAdv Mater
March 2025
Department of Engineering Mechanics, School of Aerospace Engineering, Tsinghua University, Beijing, 100084, P. R. China.
Valves are critical components in advanced fluid control systems (AFCS) and play a vital role in applications such as soft robotics and medical devices. Traditional mechanical valves often suffer from issues such as leakage and wear, which compromise the efficiency and precision of air-driven systems. Here, a superlubricity microvalve (SLMV) is developed with characteristics of zero leakage, ultralong lifespan, and self-sensing capabilities.
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