The growing need for integrating two-dimensional materials in electronic and functional devices requires the flexibility of the material. This necessitates the characterization of their mechanical properties to understand their structure under stress loading in working devices. However, it is still challenging to directly characterize the mechanical behaviours of two-dimensional materials due to difficulties in handling these naturally fragile materials. In this review, we summarize the recent studies of mechanical properties in two-dimensional materials and their characterization using various microscopy techniques. This involves advances in fundamentals including the measurements of elastic properties, and the basic understanding of how structural parameters like defects and interfaces influence the deformation and failure process of two-dimensional materials. We also discuss the developed handling techniques for transferring two-dimensional materials to the characterization platforms, with the recent advances in characterization studies based on atomic force microscopy and scanning/transmission electron microscopy. The above developments allowed the direct observation of unconventional mechanisms behind the deformation behaviour of two-dimensional materials, including plastic deformation, interlayer slip, phase transition and nanosized cracking. We then discuss the applications related to the mechanics of two-dimensional materials, including structural materials, electronic and optoelectronic properties, and further conclude with the opportunities and challenges in this field.
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http://dx.doi.org/10.1039/d4nr05171h | DOI Listing |
Chemphyschem
March 2025
Universität Siegen, Physikalische Chemie, Adolf-Reichwein-Str. 2, 57076, Siegen, GERMANY.
Organic-inorganic halocuprates(I) form a promising class of light-emitting materials with high photoluminescence (PL) quantum yield. However, the understanding of their emission properties and the PL mechanism is still limited. Here, we investigate thin films of bis(tetrapropylammonium) hexa-µ-bromo-tetrahedro-tetracuprate(I), [N(C3H7)4]2[Cu4Br6], which has a zero-dimensional (0D) molecular salt structure containing [Cu4Br6]2- ions.
View Article and Find Full Text PDFACS Nano
March 2025
School of Chemical Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, China.
The self-assemblies of topological complex block copolymers, especially the AB type miktoarm star ones, are fascinating topics in the soft matter field, which represent typical self-assembly behaviors analogous to those of biological membranes. However, their diverse topological asymmetries and versatile spontaneous curvatures result in rather complex phase separations that deviate significantly from the common mechanisms. Thus, numerous trial-and-error experiments with tremendous parameter space and intricate relationships are needed to study their assemblies.
View Article and Find Full Text PDFInt J Pharm
March 2025
New Jersey Institute of Technology, Otto H. York Department of Chemical and Materials EngineeringNewark, NJ 07102-1982, USA. Electronic address:
Small volume dissolution systems are commonly used in dissolution testing, primarily in method development for low dose formulations compared to standard dissolution apparatuses used with evaluation of larger formulations. This is typically done because of cost savings associated with using smaller media volumes and sample sizes, to overcome the lack of material in early development, and to provide higher analytical sensitivity and discrimination ability. The Chinese Pharmacopoeia (CP) includes a small dissolution apparatus in their list ("Method 3 (Small Vessel)") (The State Pharmacopoeia Commission of P.
View Article and Find Full Text PDFEur J Dent
March 2025
Department of Prosthodontics, Faculty of Dentistry, Chiang Mai University, Chiang Mai, Thailand.
Objective: Despite the emergence of numerous three-dimensional (3D) printed provisional resin, there are no conclusive guidelines for repairing them. This study aims to investigate the effects of different repair materials and surface treatments on the shear bond strength of 3D-printed provisional resin.
Materials And Methods: A total of 180 3D-printed resin specimens underwent six surface treatments: no surface treatment (control), silicon carbide paper (SP), sandblasting with aluminum oxide (SB), SP followed by SB (SP + SB), SP with bonding agent (SP + BD), and SB with bonding agent (SB + BD).
J Colloid Interface Sci
March 2025
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China; Heilongjiang Provincial Key Laboratory of Advanced Quantum Functional Materials and Sensor Devices, Harbin 150001, China. Electronic address:
Optical synaptic devices (OSDs) have neuromorphic vision sensing capability showing great potential in breaking the von Neumann bottleneck and facilitating future artificial vision systems. However, the applications of two-dimensional (2D) material-based OSDs are still impeded by complicated structures, preparation techniques and so on. In this work, we propose a 2D OSD based on BiSe films prepared by a chemical vapor deposition method followed by an in-situ thermal treatment.
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