Recent Progress in the Design and Application of Strong Metal-Support Interactions in Electrocatalysis.

The strong metal-support interaction (SMSI) in supported metal catalysts represents a crucial factor in the design of highly efficient heterogeneous catalysts. This interaction can modify the surface adsorption state, electronic structure, and coordination environment of the supported metal, altering the interface structure of the catalyst. These changes serve to enhance the catalyst's activity, stability, and reaction selectivity. In recent years, a multitude of researchers have uncovered a range of novel SMSI types and induction methods including oxidized SMSI (O-SMSI), adsorbent-mediated SMSI (A-SMSI), and wet chemically induced SMSI (Wc-SMSI). Consequently, a systematic and critical review is highly desirable to illuminate the latest advancements in SMSI and to deliberate its application within heterogeneous catalysts. This article provides a review of the characteristics of various SMSI types and the most recent induction methods. It is concluded that SMSI significantly contributes to enhancing catalyst stability, altering reaction selectivity, and increasing catalytic activity. Furthermore, this paper offers a comprehensive review of the extensive application of SMSI in the electrocatalysis of hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and carbon dioxide reduction reaction (CORR). Finally, the opportunities and challenges that SMSI faces in the future are discussed.