The increasing concern regarding pharmaceutical contaminants in the environment, particularly ibuprofen (IBU) and naproxen (NPX), has led to extensive research on effective methods for removing these pollutants. This review evaluates the use of metal organic frameworks (MOFs) for the removal of IBU and NPX from water, summarizing findings from studies published between 2010 and 2024, sourced from Google Scholar, ScienceDirect, and Scopus. The analysis shows that 68.3% of the reviewed studies focused on IBU and 31.7% on NPX. Analytical techniques such as XRD, FESEM, FTIR, XPS and BET were frequently used, appearing in 95.12, 78, 75.6, 56.1%, and 34.15% of the studies, respectively. This study demonstrated that MOFs, including Pd@MIL-100(Fe), UiO-67@β-CD-NP, HSO₃-MIL-53(Fe), and UiO-66-MOF, are capable of achieving complete removal of the targeted pharmaceuticals. The findings indicate that the key factors influencing removal efficiency include solution pH, MOF dosage, and adsorption mechanisms. This review concludes that MOFs, particularly those following the Langmuir adsorption isotherm model and PSO adsorption kinetics, are promising for the effective removal of IBU and NPX. These results highlight the potential of MOFs in addressing pharmaceutical contamination and suggest further research, particularly in optimizing MOF structures for environmental applications.
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http://dx.doi.org/10.1007/s11356-025-36165-1 | DOI Listing |
J Am Chem Soc
March 2025
Institute for Decarbonization Materials, University of California, Berkeley, California 94720, United States.
The efficient removal of CO from exhaust streams and even directly from air is necessary to forestall climate change, lending urgency to the search for new materials that can rapidly capture CO at high capacity. The recent discovery that diamine-appended metal-organic frameworks can exhibit cooperative CO uptake via the formation of ammonium carbamate chains begs the question of whether simple organic polyamine molecules could be designed to achieve a similar switch-like behavior with even higher separation capacities. Here, we present a solid molecular triamine, 1,3,5-tris(aminomethyl)benzene (TriH), that rapidly captures large quantities of CO upon exposure to humid air to form the porous, crystalline, ammonium carbamate network solid TriH(CO)·HO (TriHCO).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2025
University of Eastern Finland, Deaprtment of Chemistry, Yliopistokatu 7, 80101, Joensuu, FINLAND.
We studied a family of coordination compounds with short intramolecular spatial separation between an organic chromophore and a metal centre. The specific geometry was realized by means of anthracene-functionalized tertiary aryl phosphanes. Their silver and gold complexes (1, 2) operate as conventional fluorophores, with photophysical behavior defined by anthracene-localized allowed transitions.
View Article and Find Full Text PDFWaste Manag Res
March 2025
Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL, USA.
Landfill leachate characteristics vary depending on the type of waste facilities accept, such as municipal solid waste (MSW), construction and demolition debris (CDD) and MSW incineration (MSWI) ash. Optimizing disposal and treatment practices requires a thorough understanding of the behaviour of leachates from different classifications of refuse. This study provides a critical analysis of variation in leachate quality among over 80 sites based on landfill category: MSW, bulky debris, MSWI ash and MSW-MSWI ash co-disposal.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
March 2025
Department of Environmental Medicine, Faculty of Public Health, Institute of Health Protection, Slovak Medical University in Bratislava, Limbová 2651/12, 833 03, Bratislava, Slovakia.
Approximately 5 years ago, we proposed the establishment of a new category of ototoxicants: environmental ototoxicants, in addition to the recognized categories of occupational and drug-related ototoxicants. Since the publication of our review, the scientific literature has confirmed the potential for hearing impairment (HI) caused by the general population's exposure to various chemicals. However, the extent of this exposure's contribution to the global incidence of hearing loss (HL) has yet to be estimated.
View Article and Find Full Text PDFJ Fluoresc
March 2025
Department of English, Easwari Engineering College, Chennai, India.
Fluorescence-based photoinduced electron transfer (PET) has garnered significant attention in the molecular recognition field in recent years because of its unique and desirable photophysical properties. Recent advancements in PET-based chemosensors have demonstrated their potential for real-time monitoring of pollutants such as heavy metals, pesticides, and organic contaminants in various environmental matrices. This review emphasizes the recent advancements in fluorogenic and chromogenic PET-based chemosensors based on Anthracene, Imidazole, Indole, Pyrrole, Thiazole, Naphthalene, Quinoline, Calix[4]arene, Fluorescein, Quantum Dots, Schiff base compounds and also focusing on their molecular design, sensing mechanisms, and photophysical properties reported from the year 2011 to 2024.
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