Silicon-based broadband photodetectors (BBPDs) are extensively utilized in both the civilian and military fields due to their advanced fabrication processes and superior optoelectronic properties. However, most silicon-based BBPDs exhibit significantly reduced response in the visible range compared to the near-infrared band, which limits their further application in advanced optoelectronic systems. In this study, a visible-light-enhanced TiCT MXene/Si NW heterojunction BBPD is constructed by employing a small diameter silicon nanowire (Si NW) array. TiCT MXene exhibits unique electrical and optical properties, especially high conductivity and transparency, which significantly enhance the optoelectronic performance of the device. Device analysis revealed that the photoresponse of the device in the visible light band increases as the diameter of Si NWs gradually decreases from 200 nm to 100 nm. Furthermore, the device with a Si NW diameter of 120 nm achieves a responsivity of ∼520 mA W under 660 nm illumination, comparable to that in the near-infrared band (532 mA W at 910 nm). Theoretical simulations suggest that this unique photoelectric characteristic is linked to leaky mode resonances (LMRs) in small-diameter Si NWs. These results demonstrate that small diameter Si NWs are potential building blocks for low-cost and high-performance silicon-based BBPDs in the future.
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http://dx.doi.org/10.1039/d4nr04700a | DOI Listing |
ChemMedChem
March 2025
Donghua University, Pharmaceutical Science & Technology, CHINA.
A novel pheophorbide derivative, trimethyl-152-[L-aspartyl]pheophorbide a was synthesised and investigated for anti-tumor activity. The prepared photosensitizer had good absorption in the phototherapeutic window and high ROS yields. It exhibited excellent phototoxicity higher than reference compound m-THPC when irradiated by 650 nm light in vitro, and obvious photodynamic anti-tumor effect in vivo.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Institute of Inorganic and Analytical Chemistry, University of Münster, Corrensstrasse 28/30, Münster D-48149, Germany.
Lithium argyrodites LiPS ( = Cl, Br, I) are a promising class of solid-state electrolytes with the potential to achieve high conductivities (>10 mS·cm) necessary for use in solid-state batteries. Previous research has shown that structural factors, in particular, site disorder between the sulfide and halide anions, can impact the ionic conductivity of lithium argyrodites. One current hypothesis for this correlation between anion site disorder and ionic transport is a connection to the lithium-ion substructure.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Department of Chemistry, and FQRNT Center for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.
Carbenes are critical intermediates in organic chemistry, recognized for their exceptional reactivity and versatility. However, conventional methods for carbene generation are often associated with safety risks and hazardous procedures. This study presents a Ga-ZnO nanosheets photocatalyst with a (100) preferred orientation, featuring abundant refined frustrated Lewis pair (FLP) sites, excellent light absorption, and efficient charge transport properties.
View Article and Find Full Text PDFLangmuir
March 2025
Jiangxi Province Key Laboratory of Light Alloy, School of Advanced Manufacturing, Nanchang University, Nanchang 330031, P.R. China.
Herein, a superhydrophobic surface was designed and fabricated based on the "lotus effect" construction mechanism. The zeolitic imidazolate framework (ZIF-90) micro-nanoparticles were initially synthesized via a one-pot method, combined with long-chain stearic acid (STA), and subsequently embedded in polyvinyl butyral (PVB) to form a superhydrophobic surface at room temperature. The superhydrophobic surface demonstrated mechanical stability and retained its superhydrophobicity with a water contact angle (CA) greater than 150°, even at a wear distance of 400 cm.
View Article and Find Full Text PDFPLoS One
March 2025
Faculty of Education, Mie University, Mie, Japan.
This study is the first in Japan to prospectively examine the relationship between walking to and from school and physical activity in primary school children. A total of 76 participants completed baseline and follow-up assessments, and their mean age was 9.6 ± 1.
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