Solar-driven photoelectrochemical (PEC) cells, sensitized by colloidal quantum dots (QDs), are emerging as a promising approach for solar-to-fuel conversion, including hydrogen evolution and peroxide production. The high absorption coefficient and customizable size/composition/shape of QDs can effectively enhance and broaden the light absorption capabilities of the system. Additionally, QD-based heterostructures can facilitate carrier transfer, thereby enhancing the overall performance. To date, the photocurrent density of QD based photoelectrodes for water splitting has significantly surpassed that of conventional metal oxides and sulfides. However, despite recent advances in enhancing the photocurrent density of QD-based photoelectrodes, long-term operational stability remains a key challenge for their practical applications. Few studies so far have investigated in depth the stability mechanism of QD-based PEC cells alongside potential fabrication improvements. In this Review, we first discuss the dominant factors and mechanisms responsible for the deterioration of both QDs and QD-based PEC devices. Subsequently, we outline the prevalent processing techniques and effective strategies for the fabrication of durable PEC cells. Finally, future perspectives and research directions in this field are proposed.
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