Waste-to-energy conversion via pyrolysis has attracted increasing attention recently owing to its multiple uses. Among the products of this process, biochar stands out for its versatility, with its yield influenced by various factors. Extensive and labor-intensive experimental testing is sometimes necessary to properly grasp the output distribution from various feedstocks. Nonetheless, data-driven predictive models using large-scale historical experiment records can provide insightful analysis of projected yields from a variety of biomass materials, hence overcoming the challenges of empirical modeling. As such, five modern approaches available in modern machine learning are employed in this study to develop the biochar yield prediction models. The Lasso regression, Tweedie regression, random forest, XGBoost, and Gradient boosting regression were employed. Out of these five XGBoost was superior with a training mean squared error (MSE) of 1.17 and a test MSE of 2.94. The XGBoost-based biochar yield model shows excellent performance with a strong predictive accuracy of the R values as 0.9739 (training) and 0.8875 (test). The mean absolute percentage error value was only 2.14% in the training phase and 3.8% in the testing phase. Precision prognostic technologies have broad effects on sectors including biomass logistics, conversion technologies, and effective biomass utilization as renewable energy. Leveraging SHAP based on cooperative game theory, the study shows that while ash and moisture lower biochar yield, FPT, nitrogen, and carbon content significantly boost it. Small variables like heating rate and volatile matter have a secondary impact on production efficiency.
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http://dx.doi.org/10.1038/s41598-025-91450-w | DOI Listing |
Environ Dev Sustain
November 2023
Geography Department, Faculty of Science and Engineering, Swansea University, Swansea, Wales SA2 8PP UK.
The disposal of faecal sludge from non-networked sanitation amenities leads to contamination of the surrounding environment and increasing public health problems across developing countries. Permanent solutions to deal with faecal sludge are required to solve the sanitation crisis and achieve the Sustainable Development Goal (SDG) 6 "ensure availability and sustainable management of water and sanitation for all" by 2030. Full-scale pyrolysis of faecal sludge in developing countries is fast becoming a safe and long-term option.
View Article and Find Full Text PDFACS Omega
March 2025
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781039, India.
biomass's thermal degradation was investigated in a nonisothermal thermogravimetric analyzer at four heating rates. Iso-conversional methods (differential Friedman, Kissinger-Akahira-Sunose, Ozawa-Flynn-Wall, Starink, and distributed activation energy) were used to analyze the kinetic and thermodynamic parameters. The pre-exponential factor and activation energy for all iso-conversional processes varied from 10 to 10 min and 168.
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March 2025
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, Assam 781039, India.
Waste flowers constitute a significant portion of organic waste, offering the potential for sustainable waste management through pyrolysis. This study explores the pyrolysis behavior, kinetic parameters, and biochar production from waste flowers. Thermogravimetric analysis (TGA) was employed to examine thermal degradation characteristics under varying heating rates (10, 20, and 50 °C min).
View Article and Find Full Text PDFJ Environ Manage
March 2025
National-Local Joint Engineering Research Center of Biomass Refining and High-Quality Utilization, Institute of Urban and Rural Mining, Changzhou University, Changzhou, 213164, China; Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou University, Changzhou, 213164, China; CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, 510640, China. Electronic address:
In view of the food waste (FW) as well as its digestate are both the organic sources of municipal solid waste, this study explored the anaerobic fermentation (AF) and following pyrolysis carbonization to co-disposal the two wastes for carbon resource recovery, including short chain organic acid (SCOAs), pyrolysis gas and biochar. Results indicated that both the rate and yield of SCOAs production both increase with the rising ratio of biogas sludge (BS) to FW, enhancing the soluble carbon recovery. The highest SCOAs production of 474.
View Article and Find Full Text PDFJ Environ Manage
March 2025
Department of Geology and Geochemistry, Oil and Gas Institute-National Research Institute, 25A Lubicz St., Kraków, 31-503, Poland.
In this study, two different microbial pretreatments (fungal and fungal-bacterial consortia) of sunflower seed husks were used to assess their impact on pyrolysis performance and the resulting biochar parameters. Both treatments reduced the activation energy of the pyrolysis process and shortened the temperature range of pyrolysis, making the process easier to initiate and sustain. Moreover, they enhanced the yield of fractions with compounds containing low (C-C) and medium (C-C) number of carbon atoms at 400 and 500 °C.
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