Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 197
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 197
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 271
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3145
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Org Lett
Jiangxi Province Key Laboratory of Natural and Biomimetic Drugs Research, College of Chemistry and Materials, Jiangxi Normal University, Nanchang 330022, China.
Published: February 2025
By means of simple Rh catalysis, the direct activation of the -C-H bond in aryl enaminones has been realized with the enaminone structure as a traceless directing fragment. The products resulting from C-H alkenylation and further annulation via intramolecular C-H bond addition could be accessed depending upon the structure of alkenes. The annulated products could be used for the easy synthesis of valuable 2-aza-fluorenones in a one-pot operation by employing NHOAc.
Download full-text PDF |
Source |
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http://dx.doi.org/10.1021/acs.orglett.5c00213 | DOI Listing |
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