Long spin lifetimes are crucial for maintaining robust spin states during propagation in spintronic devices. Spin-orbit coupling (SOC) in chiral hybrid perovskites can induce chirality-dependent spin splitting, facilitating the manipulation of spin polarization. In this study, we introduce a chiral organic molecule, (/)-4-(aminoethyl)piperidinium (4AEP), into iodide-lead-based structures to synthesize chiral [(/)-4AEP]PbI crystals and thin films. Using circularly polarized pump-probe techniques, we examine the carrier spin dynamics in [(/)-4AEP]PbI. Our results demonstrate that chirality-induced spin splitting significantly enhances the spin-polarization lifetime, achieving a spin splitting of approximately 130 meV at the valence band maximum and spin lifetimes exceeding 1 ns. Density functional theory (DFT) calculations reveal that opposite spin states exist in the - and -chiral samples with substantial spin splitting. These findings highlight the potential of chiral hybrid perovskites for spintronics applications.
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