An enantioselective preparation of vinyl, alkyl-substituted chiral α-stereogenic acrylates is reported using two consecutive steps of Ir-catalysed allylic alkylation of aliphatic allylic acetates with phosphonates and Horner-Wadsworth-Emmons olefination. Unlike commonly utilised iridium-phosphoramidite catalysts, Krische's catalyst was uniquely effective in promoting highly regio- and enantioselective reactions of alkyl-substituted allylic substrates, thus constituting a significant alternative to the known protocol.
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