The expansion of the Internet of Things (IoT) has rendered wireless passive, highly stable, and room-temperature gas sensors indispensable for sensor applications. In this work, a room-temperature surface acoustic wave (SAW) HS sensor based on a thin film of nano-mesh woven with BiS nanoribbons was successfully designed and prepared. The impact of varying inorganic salts solution ligand substitution of long-chain organic ligands of BiS films on performance was assessed. Notably, the responses of the sensors following ligand substitution exhibited improvement to varying degrees. In particular, the Cu(NO)-treated sensor to 10 ppm HS was 203% of that of the untreated sensor. Furthermore, the impact of visible light activation on sensor performance was assessed. The results show the sensor has a high sensitivity to HS molecules under yellow light activation at room temperature, with excellent selectivity, fast response speed and low detection limit. The sensor exhibited a response to 10 ppm HS under yellow light activation that was approximately equal ~ two times greater than the response observed in a dark environment. This work provides a novel approach to enhance the performance of room-temperature SAW HS sensors.
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http://dx.doi.org/10.3390/s25041122 | DOI Listing |
ChemMedChem
March 2025
Donghua University, Pharmaceutical Science & Technology, CHINA.
A novel pheophorbide derivative, trimethyl-152-[L-aspartyl]pheophorbide a was synthesised and investigated for anti-tumor activity. The prepared photosensitizer had good absorption in the phototherapeutic window and high ROS yields. It exhibited excellent phototoxicity higher than reference compound m-THPC when irradiated by 650 nm light in vitro, and obvious photodynamic anti-tumor effect in vivo.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Department of Chemistry, and FQRNT Center for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.
Carbenes are critical intermediates in organic chemistry, recognized for their exceptional reactivity and versatility. However, conventional methods for carbene generation are often associated with safety risks and hazardous procedures. This study presents a Ga-ZnO nanosheets photocatalyst with a (100) preferred orientation, featuring abundant refined frustrated Lewis pair (FLP) sites, excellent light absorption, and efficient charge transport properties.
View Article and Find Full Text PDFPLoS One
March 2025
Faculty of Education, Mie University, Mie, Japan.
This study is the first in Japan to prospectively examine the relationship between walking to and from school and physical activity in primary school children. A total of 76 participants completed baseline and follow-up assessments, and their mean age was 9.6 ± 1.
View Article and Find Full Text PDFPlant Cell
March 2025
Institute of Molecular Biology, University of Oregon, Eugene, OR 97405.
The D1 subunit of photosystem II is subject to photooxidative damage. Photodamaged D1 must be replaced with nascent D1 to maintain photosynthesis. In plant chloroplasts, D1 photodamage regulates D1 synthesis by modulating translation initiation on psbA mRNA encoding D1.
View Article and Find Full Text PDFPlant Physiol
March 2025
School of Life Sciences, Peking University, Beijing 100871, China.
The cytochrome b6f complex (Cyt b6f) plays pivotal roles in both linear and cyclic electron transport of oxygenic photosynthesis in plants and cyanobacteria. The four large subunits of Cyt b6f are responsible for organizing the electron transfer chain within Cyt b6f and have their counterparts in the cytochrome bc1 complex in other bacteria. The four small subunits of Cyt b6f are unique to oxygenic photosynthesis, and their functions remain to be elucidated.
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