Leaching of hazardous substances, particularly heavy metals, from incineration bottom ash (IBA) presents a significant challenge for its utilization in construction. Laboratory leaching tests are commonly used to assess the environmental compliance of IBA; however, they are conducted under controlled conditions that do not directly simulate real field situations, which lead to discrepancies between laboratory results and field monitoring due to the lack of robust linking with material- and site-specific parameters. This can lead to misjudgment of risks or unnecessary precautions. This study evaluates the long-term leaching behavior of a full-scale carriageway using IBA as a subbase material through a release model based on laboratory leaching tests. Column leaching and compacted granular leaching tests were conducted to simulate percolation- and diffusion-controlled scenarios. Additionally, the interaction between the underlying reclaimed sand (hereafter referred to as "engineered soil") and IBA leachate was studied, considering the buffering capacity of the vadose zone to prevent the transport of elements to groundwater. A one-dimensional advection-dispersion transport model, incorporating site-specific parameters, was applied to assess the potential threat to groundwater over time. The release and transport models were combined to reflect progressive changes in source terms and arrival at the groundwater table. Various geochemical and hydrogeological parameters were determined through laboratory testing, field monitoring, and data collection to strengthen the model. The simulation spans from 100 to over 10,000 years, depending on soil retardation, and fully covers the typical lifespan of a road. Results indicated that metal elements may be influenced by different leaching scenarios, suggesting that appropriate measures can reduce leaching potential. Additionally, enhancing soil attenuation is crucial in slowing the transport of elements to groundwater.
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http://dx.doi.org/10.1016/j.wasman.2025.02.031 | DOI Listing |
Environ Toxicol Chem
March 2025
The Wildlife Toxicology Laboratory, Texas Tech University, Lubbock, Texas, 79409-3290USA.
Parasites are a significant health concern for livestock and domestic animals and much effort has been invested in the development, testing, and implementation of treatments. There has, however, been relatively little done to treat wild animal populations for parasites. Northern bobwhite (Colinus virginianus) is a species of conservation interest, that could benefit from anti-parasite treatment.
View Article and Find Full Text PDFACS Omega
March 2025
Nuclear and Energy Research Institute, IPEN-CNEN/SP, Av. Prof. Lineu Prestes, São Paulo 2242, Brazil.
This study examines the geopolymerization potential of sewage sludge ash (SSA) for immobilizing radioactive waste through a series of experimental phases. The initial phase of the study involved processing sewage sludge from three different treatment plants, followed by calcination and subsequent characterization. The initial synthesis of geopolymers was conducted using 100% SSA, followed by compressive strength testing.
View Article and Find Full Text PDFEnviron Res
March 2025
Department of Environmental Engineering, Beijing University of Technology, Beijing 100124, P. R. China; National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology, Beijing University of Technology, Beijing 100124, P. R. China. Electronic address:
The leaching of toxic metals is still problematic for heterogeneous metal catalysts in activating peracetic acid (PAA). Herein, CoFe/U-ZrO was synthesized by loading CoFe onto the metal-organic framework (UiO-66) derived ZrO (U-ZrO) for PAA activation. The high porosity and specific surface area of UiO-66 enable efficient embedding and uniform dispersion of CoFe particles into pore channels.
View Article and Find Full Text PDFChemosphere
March 2025
LSRE-LCM - Laboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465, Porto, Portugal; ALiCE - Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465, Porto, Portugal.
The textile industry contributes to 2-10% of global greenhouse gas emissions, water extraction, and biodiversity loss, consuming 93 billion cubic meters of water annually with low reuse rates. Coagulation/flocculation is commonly used for industrial wastewater treatment, typically using conventional coagulants. Recently, interest in natural alternatives, particularly tannin-based coagulants, has grown.
View Article and Find Full Text PDFSci Rep
March 2025
Department of Chemistry, Yasouj University, 75918-74831, Yasouj, Iran.
In this work, graphene oxide (GO) nanoparticles were synthesized and subsequently modified using 3-aminopropyltrimethoxysilane (APTMS). An Anderson-type polyoxometalate [(CH)N][CrMoO(OH)] was then immobilized on the surface of the modified graphene oxide nanoparticles. The obtained catalyst was characterized using Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDS), inductively coupled plasma (ICP), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Raman spectroscopy, and X-ray diffraction (XRD).
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