The problem of an optimal mapping between Hilbert spaces IN and OUT, based on a series of density matrix mapping measurements ρ^{(l)}→ϱ^{(l)}, l=1⋯M, is formulated as an optimization problem maximizing the total fidelity F=∑_{l=1}^{M}ω^{(l)}F(ϱ^{(l)},∑_{s}B_{s}ρ^{(l)}B_{s}^{†}) subject to probability preservation constraints on Kraus operators B_{s}. For F(ϱ,σ) in the form that total fidelity can be represented as a quadratic form with superoperator F=∑_{s}〈B_{s}|S|B_{s}〉 (either exactly or as an approximation) an iterative algorithm is developed. The work introduces two important generalizations of unitary learning: (1) IN/OUT states are represented as density matrices; (2) the mapping itself is formulated as a mixed unitary quantum channel A^{OUT}=∑_{s}|w_{s}|^{2}U_{s}A^{IN}U_{s}^{†} (no general quantum channel yet). This marks a crucial advancement from the commonly studied unitary mapping of pure states ϕ_{l}=Uψ_{l} to a quantum channel, which allows us to distinguish probabilistic mixture of states and their superposition. An application of the approach is demonstrated on unitary learning of density matrix mapping ϱ^{(l)}=Uρ^{(l)}U^{†}, in this case a quadratic on U fidelity can be constructed by considering sqrt[ρ^{(l)}]→sqrt[ϱ^{(l)}] mapping, and on a quantum channel, where quadratic on B_{s} fidelity is an approximation-a quantum channel is then obtained as a hierarchy of unitary mappings, a mixed unitary channel. The approach can be applied to studying quantum inverse problems, variational quantum algorithms, quantum tomography, and more. A software product implementing the algorithm is available from the authors.
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http://dx.doi.org/10.1103/PhysRevE.111.015302 | DOI Listing |
Nano Lett
March 2025
State Key Lab for Mesoscopic Physics and Frontiers Science Center for Nano-optoelectronics, School of Physics, Peking University, Beijing 100871, China.
A programmable 2H-MoTe floating-gate field-effect transistor (FGFET)-based complementary metal oxide semiconductor (CMOS) array has been fabricated on the grown substrate. Coplanar grown metallic 1T'-MoTe serves as the source and drain electrodes. The conductive type of the 2H-MoTe channel is manipulated by a top-gate engineering method.
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March 2025
State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China.
In this study, we construct a quantum well effect-based two-dimensional Z-scheme superlattice heteronanostructure photocatalyst constructed from hydrogen-bonded porphyrin organic frameworks (HOFs) and carbon nitride. Porphyrin HOFs extend spectral absorption, while their π-conjugation and electron density variations significantly enhance charge separation and exhibit favorable alignment with the energy levels of carbon nitride, thereby enabling efficient charge transfer. Carboxylic acid channels in the HOFs further promote the decomposition of water molecules, thereby boosting hydrogen production.
View Article and Find Full Text PDFJ Comput Chem
March 2025
Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas, USA.
In photopharmacology, molecular photoswitches enable light-controlled drug activities, offering precision in targeting biomolecular functions while minimizing side effects. Photostatins (PSTs) are photoswitchable analogs of combretastatin A-4 (CA4), designed to inhibit tubulin polymerization for cancer treatment. However, the influence of substituents and molecular environments on their photochemistry remains unclear.
View Article and Find Full Text PDFAdv Mater
March 2025
Electronic Information School, Wuhan University, Wuhan, 430072, China.
Recent advancements in multidimensional multiplexing have paved the way for meta-optics encryption to be a viable solution to next-generation information storage and encryption security. However, challenges persist in increasing simultaneously modulated dimensions while minimizing structural complexity. Here, a novel single-cell order-decoupling method is proposed for the realization of a multidimensional encrypted meta-optics storage system.
View Article and Find Full Text PDFNat Mater
March 2025
MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, Institute of Optoelectronics & Nanomaterials, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, China.
Currently, p-type two-dimensional (2D) materials lag behind n-type ones in both quantity and performance, hindering their use in advanced p-channel transistors and complementary logic circuits. Non-layered materials, which make up 95% of crystal structures, hold the potential for superior p-type 2D materials but remain challenging to synthesize. Here we show a vapour-liquid-solid-solid growth of atomically thin (<1 nm), high-quality, non-layered 2D β-BiO crystals on a SiO/Si substrate.
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