The production of ultrafine particles is increasingly important, but requires special attention to mitigate environmental and energy burdens. Among available milling equipment, the air-jet mill (AJM) has major merits. AJM is applied in the pharmaceutical, catalyst, and ceramic industries to produce μm-particles with high specific surface area, high catalytic activity, and effective ad/absorbent properties. A small (D = 0.1 m) and a larger (D = 0.4 m) AJM were investigated with lactose as a model pharmaceutical compound. The particle size distribution (PSD) and the specific surface area (SSA) of the milled product were determined. Milling efficiencies and required energy were modeled by the Rittinger approach. Environmental concerns of dust emissions and associated health hazards were dealt with by applying a sintered metal fibre filtration. The findings provide design recommendations for AJMs in view of sustainable and efficient operation.
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http://dx.doi.org/10.1016/j.jenvman.2025.124401 | DOI Listing |
Int J Biol Macromol
March 2025
Center of Chemical, Pharmaceutical and Food Sciences, Innovation and Solutions in Chemistry Laboratory, Federal University of Pelotas, Eliseu Maciel St., s/n, Pelotas, RS 96160-000, Brazil; Postgraduate Program in Biotechnology, Federal University of Pelotas, Eliseu Maciel St., s/n, Pelotas, RS 96160-000, Brazil; Postgraduate Program in Materials Science and Engineering, Technology Development Center, Federal University of Pelotas, 96010-000 Pelotas, Rio Grande do Sul, Brazil. Electronic address:
Ultrafine fibers are gaining attention for their unique properties and wide-ranging applications. Among production techniques, electrospinning stands out for its cost-effectiveness, simplicity, and control over fiber structure and diameter. This study reports for the first time the development of ultrafine fibers using zein, a renewable protein, with the addition of fucoidan, a bioactive polysaccharide from brown algae, through electrospinning.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2025
Shandong Key Laboratory of Special Epoxy Resin, School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, Shandong, PR China. Electronic address:
While the configuration of most metal oxides hollow structures is well established, the synthesis of multinary metal sulfides with complex multi-shelled hollow structures remains in its infancy. Herein, we have developed a facile method to synthesize superhydrophilic CaZnInS double-shelled hollow structures (DSHSs) with the assistance of trisodium citrate bilamellar vesicles, which manifests higher photocatalytic hydrogen generation rate compared with normal CaZnInS single-shelled hollow structures and solid microflowers. Further construction of CdS/CaZnInS S-scheme heterostructures by in situ photodeposition of CdS ultrafine nanoparticles on CaZnInS DSHSs creates an intimate interface coupling and expansive contact region for fast interfacial charge transfer.
View Article and Find Full Text PDFScience
March 2025
Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, China.
The lattice deformation and structural evolution of perovskite films in response to electric fields, temperature, and light limit the operational endurance of solar cells. We mechanically reinforced perovskite thin films by integrating a polymer-coupled monolithic single-layer graphene interface that led to a twofold enhancement in modulus and hardness. The synergistic effect of graphene and poly(methyl methacrylate) restricted photoinduced lattice expansion and decreased the deformation ratio from 0.
View Article and Find Full Text PDFInorg Chem
March 2025
Department of Chemistry, Chonnam National University, Gwangju 61186, Republic of Korea.
We introduce a novel nonalkyl tin oxo cluster, CNU-TOC-01(4C-C), synthesized through a reflux-based solution reaction using SnCl, HO, and pyrazole, which permits scalable production and molecular customization. Using field desorption-time-of-flight mass spectrometry (FD-TOF MS) and small-angle X-ray scattering (SAXS), CNU-TOC-01(4C-C) is characterized as a cyclic cluster with the molecular formula SnCl(CNH)(CNH)HO. The cluster size was measured to be 11.
View Article and Find Full Text PDFEnviron Int
February 2025
Department of Environmental Health Science, School of Public Health, University at Albany, State University of New York, Rensselaer, NY 12144, USA; Department of Epidemiology and Biostatistics, School of Public Health, University at Albany, State University of New York, Rensselaer, NY 12144, USA. Electronic address:
Background: Health effects of ultrafine particles (UFPs) and their interactions with temperature are less studied. We investigated the risks of UFPs concentrations and extreme temperatures on hospitalizations for high-burden diseases (HBDs) in New York State (NYS).
Methods: This case-crossover study included hospitalizations for HBDs that contain ischemic heart diseases, diabetes, stroke, kidney diseases, and depression using NYS Hospital Discharge Data (2013-2018).
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