Copper(I) Halide Complex Featuring Blue Thermally Activated Delayed Fluorescence and Aggregate Induced Emission for Efficient X-ray Scintillation and Imaging.

Developing solution-processable and stable scintillators with high light yields, low detection limits and high imaging resolutions holds great significance for flexible X-ray imaging. However, attaining an optimal equilibrium among X-ray absorption capacity, exciton utilization efficiency, and decay lifetime of scintillators remains a substantial challenge. Here, a new Cu(I) halide complex was synthesized in a mild condition. It exhibits intense blue thermally activated delayed fluorescence (TADF), remarkable aggregation-induced emission (AIE) characteristic, as well as good water-oxygen stability and photochemical stability. Notably, the complex shows excellent radiation resistance and efficient radioluminescence (RL) with an ultra-low detection limit of 42.5 nGys. This superior scintillation performance can be attributed to the synergistic effect of effective X-ray absorption by the heavy CuI core, the high radiation-induced exciton utilization rate in TADF process, and the remarkable suppression of non-radiative transitions by the restriction of intramolecular motions in solid state. Furthermore, the favourable solution processability of the complex facilitates the successful fabrication of a flexible film, achieving high-quality X-ray imaging with a resolution of 17.3 lp mm. This work highlights the potential of hybrid Cu(I) halides with AIE-TADF effects for high-energy radiation detection and imaging, opening up new avenues for the exploration of cost-effective and high-performance scintillators.