In state-of-the-art optical lattice clocks, beyond-electric-dipole polarizability terms lead to a breakdown of magic wavelength trapping. In this Letter, we report a novel approach to evaluate lattice light shifts, specifically addressing recent discrepancies in the atomic multipolarizability term between experimental techniques and theoretical calculations. We combine imaging and multi-ensemble techniques to evaluate lattice light shift atomic coefficients, leveraging comparisons in a dual-ensemble lattice clock to rapidly evaluate differential frequency shifts. Further, we demonstrate application of a running wave field to probe both the multipolarizability and hyperpolarizability coefficients, establishing a new technique for future lattice light shift evaluations.
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http://dx.doi.org/10.1103/PhysRevLett.134.033201 | DOI Listing |
Adv Mater
March 2025
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, P. R. China.
P2-type NaNiMnO (NNMO) as cathode material for sodium-ion batteries (SIBs) largely suffers from continuous accumulation of local stress caused by destructive structural evolution and irreversible oxygen loss upon cycling, leading to rapid capacity degradation. Herein, a strategy of negative enthalpy doping (NED), wherein transition metal (TM) sites are substituted with 0.01 mol each Sn, Sb, Cu, Ti, Mg, and Zn to increase the stability of the TM layers, is proposed.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Polymer Science and Engineering Department, Conte Center for Polymer Science Research, University of Massachusetts Amherst, 120 Governors Drive, Amherst, Massachusetts 01003, United States.
The ability to arrange brightly fluorescent nanoscale materials into well-defined patterns is critically important in advanced optoelectronic structures. Traditional methods for doing so generally involve depositing different color quantum dot "inks," irradiating reactive (e.g.
View Article and Find Full Text PDFJ Phys Chem Lett
March 2025
International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China.
The ability to dynamically manipulate the optoelectronic and magnetic properties in functional materials under nonequilibrium conditions is essential for the advancement of quantum technologies and energy-related applications. Here, we demonstrate a novel method to regulate the optoelectronic and magnetic properties of YCoO, a representative perovskite oxide, using ultrafast vortex laser pulses coupled with nonlinear phonon interactions. Vortex light, characterized by its helical phase front and topological charge, allows selective excitation of infrared phonon modes, enabling anisotropic lattice distortions and precise modulation of material properties.
View Article and Find Full Text PDFHeliyon
February 2025
Department of Physics, Bangladesh University of Engineering and Technology, Dhaka, Bangladesh.
The low-cost hydrothermal method has been successfully applied to synthesize MnS-incorporated MoS nanoflowers (MoS/MnS). The FE-SEM, TEM, XRD, Raman, UV-VIS, and density functional theory (DFT) were used to investigate the surface morphology, structural property, optical property, and simulated optical and dielectric properties. FE-SEM and TEM images reveal the 3D flower-like structure of MoS and the flower-like structure of the nanocomposite.
View Article and Find Full Text PDFSmall
March 2025
Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China.
The self-limiting Cabrera-Mott oxidation reaction on metal surfaces provides an effective pathway for synthesizing atomically thin 2D metal oxide. Inspired by this reaction, it is proposed that solid bismuth metals can react with dissolved oxygen and water molecules in an aqueous environment, forming an ultrathin oxyhydroxide layer on their surfaces. The lattice mismatch between the surface oxyhydroxide layer and the underlying pure metal enables the mechanical exfoliation of detached 2D oxyhydroxide nanosheets.
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