Surface plasmon polaritons (SPPs) describe the excitation of photons coupled with free charge carriers at the interface of metals (visible) or doped semiconductors (infrared). While SPPs in the mid-infrared spectral range have been demonstrated in 2D materials such as graphene, their short propagation length combined with weak confinement in bulk materials has prevented real-space imaging of those SPPs. Here, we demonstrate real-space imaging of propagating SPPs on the doped semiconductors CdO and InAs with tunable plasma frequencies in the infrared via scattering-type scanning near-field optical microscopy. Adding a thin film of phase-change materials (PCMs) to these doped semiconductors increases the polariton confinement, leading to simplified SPP imaging and SPP resonator fabrication. We investigate optically written circular resonators of the plasmonic PCM InSbTe on CdO with near-field spectroscopy and Fabry-Perot resonators of the dielectric PCM GeSbTe on InAs with far-field spectroscopy. Our work enables rapid prototyping of reconfigurable SPP resonators in mid-infrared.
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http://dx.doi.org/10.1126/sciadv.adr6844 | DOI Listing |
ACS Appl Mater Interfaces
March 2025
Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, Shandong 250353, P. R. China.
Developing ideal photocatalysts for energy regeneration and environmental remediation by combining the advantages of individual semiconductors remains a significant challenge. Herein, tungsten trioxide (WO)/CuSnS S-scheme heterojunction composite photocatalysts are developed. Initially, doped oxygen vacancy (OV) was prepared on two-dimensional WO nanosheets by direct calcination method.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
March 2025
Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193 Bellaterra, Spain.
Poly(benzodifurandione) (PBFDO) has emerged as a promising n-type conductive polymer (n-CP) for organic electronic applications, particularly in thermoelectrics (TE), due to its high doping efficiency and environmental stability. Unlike most high-performance p-type polymers, high-efficiency n-CPs are limited, posing a bottleneck in the TE module performance. In this study, we use first-principles electronic structure calculations to investigate the thermodynamic conditions that favor n-doping in PBFDO, focusing on the role of the temperature, chain length, and doping concentration.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
Leiden Institute of Chemistry, Universiteit Leiden, PO Box 9502, Leiden 2300 RA, Netherlands.
Schottky diodes have been a fundamental component of electrical circuits for many decades, and intense research continues to this day on planar materials with increasingly exotic compounds. With the birth of nanotechnology, a paradigm shift occurred with Schottky contacts proving to be essential for enabling nanodevice inventions and increasing their performance by many orders of magnitude, particularly in the fields of piezotronics and piezoelectric energy harvesting. ZnO nanomaterials have proven to be the most popular materials in those devices as they possess high piezoelectric coefficients, high surface sensitivity, and low resistivity due to the high native n-type doping and low hole concentration.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, 310027 Hangzhou, China.
Organic electrochemical transistors (OECTs) are seen as some of the most promising devices in organic bioelectronics. Recent interest in OECTs is sparked by the high performance of an organic semiconductor channel material, i.e.
View Article and Find Full Text PDFJ Phys Chem Lett
March 2025
Graduate School of System Informatics, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan.
Perovskite SrTiO (STO) is a widely used semiconductor photocatalyst whose photocatalytic activity is significantly influenced by cation doping. In this work, we explore effective divalent dopants to improve the photocatalytic performance of water splitting through both theoretical and experimental approaches. First-principles calculations suggest that divalent Mg and Zn are promising dopants replacing Ti sites of STO to help mitigate charge recombination processes associated with defect levels caused by oxygen vacancies.
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