The Kibble-Zurek mechanism predicts a universal scaling behavior of the defect production when a system is slowly quenched across a critical phase transition point. Here, we discover that the universal scaling behavior across a higher-order topological phase transition does not conform to the traditional Kibble-Zurek mechanism. To explain the anomalous scaling exponent, we develop a solvable Landau-Zener model that takes into account the role of topological edge band that dominates the phase transition. For a two-dimensional boundary-obstructed higher-order topological system, the Kibble-Zurek scaling must be modified to adopt the effective dimension of topological edge band instead of the real physical dimension. We also find that across the boundary-obstructed higher-order topological phase transition, boundary conditions can drastically modify the scaling behaviors. For comparison, we investigate the slow quench dynamics across the bulk-obstructed phase transitions and a single multicritical point, which obeys the Kibble-Zurek mechanism with physical dimension.
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http://dx.doi.org/10.1103/PhysRevLett.134.010409 | DOI Listing |
Inorg Chem
March 2025
Key Laboratory of High-Temperature and High-Pressure Study of the Earth's Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550081, China.
In situ high-pressure single-crystal X-ray diffraction and Raman spectroscopy analyses were performed on a natural bismutotantalite with an α-BiTaO structure. The results indicate that α-BiTaO transforms into an orthorhombic phase (HP γ-BiTaO), likely through an intermediate orthorhombic phase (HP β-BiTaO). The transition pressures are 11.
View Article and Find Full Text PDFAdv Mater
March 2025
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, P. R. China.
P2-type NaNiMnO (NNMO) as cathode material for sodium-ion batteries (SIBs) largely suffers from continuous accumulation of local stress caused by destructive structural evolution and irreversible oxygen loss upon cycling, leading to rapid capacity degradation. Herein, a strategy of negative enthalpy doping (NED), wherein transition metal (TM) sites are substituted with 0.01 mol each Sn, Sb, Cu, Ti, Mg, and Zn to increase the stability of the TM layers, is proposed.
View Article and Find Full Text PDFAdv Mater
March 2025
School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China.
The delicate construction of electrocatalysts with high catalytic activity is a strategic method to enhance the kinetics of lithium-sulfur batteries (LSBs). Adjusting the local structure of the catalyst is always crucial for understanding the structure-activity relationship between atomic structure and catalyst performance. Here, in situ induction of electron-deficient B enables phase engineering MoC, realizing the transition from hexagonal (h-MoC) to cubic phase (c-B-MoC).
View Article and Find Full Text PDFCells
February 2025
Department of Pharmaceutical Sciences, The Skaggs School of Pharmacy and Pharmaceutical Sciences, The University of Colorado Anschutz Medical Campus, Aurora, CO 80045, USA.
The second and third most frequently diagnosed cancers worldwide are breast (2.3 million new cases) and colorectal (1.9 million new cases), respectively.
View Article and Find Full Text PDFDalton Trans
March 2025
Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia.
Carbon is nothing less than a rock star in the world of research on allotropes which has a tremendous ability to form several simple and complex allotropic structures of various sp, sp and sp hybridizations, thanks to its flexible chemical structure. By high-pressure experimental and theoretical approaches, new carbon forms were synthesized from known carbon structures. Herein, we report the phase transition from amorphous carbon nanoparticles to a novel thermodynamically stable carbon allotropic structure, denominated as SD carbon (Sivakumar-Dai carbon), obtained through the impact of acoustic shock waves with a transient pressure of 16.
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