Gallium-based liquid metals hold promises for applications in stretchable electronics and beyond. However, these materials often encounter notable resistance increases during stretching and have negligible permeability to gases and liquids. This study presents an in situ structural transformation mechanism to create stretchable and permeable liquid metal micromeshes with strain-insensitive resistance. These micromeshes are fabricated by spin-coating liquid metal onto microfiber textiles and subjecting them to several stretching cycles. Consequently, the micromeshes transform from a smooth finish to wrinkled textures due to the growth in their oxide nanoskins. The distinct microstructure alters the stretching-relaxing mode to folding-unfolding, thereby minimizing fluctuations in resistance. The practical significance of this development is demonstrated through the fabrication of wearable heaters and LED matrices using transformed liquid metal micromeshes. Moreover, when integrated into Janus textiles featuring unidirectional water transport, these micromesh conductors act as sensing electrodes capable of acquiring high-fidelity biopotentials, even during intense sweating. These advancements highlight the capability of ambient air as a powerful reactive environment for tailoring the properties of microscale liquid metals.
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http://dx.doi.org/10.1002/adma.202417799 | DOI Listing |
Adv Mater
March 2025
Frontier Institute of Science and Technology (FIST), Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, China.
Compression strongly degrades the electrical conductivity of the liquid-metal-based circuits because the liquid state is prone to be squashed. Here, a new compressible and stretchable biphasic liquid-solid self-healing circuit is proposed by filling GalnSn-BilnSn biphasic metal into micropillar-embedded channels. The underlying BilnSn solid alloy layer serves as a compression resistance layer, while the upper GalnSn liquid metal layer enables the real-time filling of the cracks in the solid layer under large deformations, resulting in autonomous self-healing and maintenance of conductivity under both stretching and compression.
View Article and Find Full Text PDFNanomaterials (Basel)
March 2025
Collaborative Innovation Center for Nanomaterials & Devices, Innovation Institute for Advanced Nanofibers, College of Physics, Qingdao University, Qingdao 266071, China.
Contact-electro-catalysis (CEC) has emerged as a promising catalytic methodology, integrating principles from solid-liquid triboelectric nanogenerators (SL-TENGs) into catalysis. Unlike conventional approaches, CEC harnesses various forms of mechanical energy, including wind and water, along with other renewable sources, enabling reactions under natural conditions without reliance on specific energy inputs like light or electricity. This review presents the basic principles of CEC and discusses its applications, including the degradation of organic molecules, synthesis of chemical substances, and reduction of metals.
View Article and Find Full Text PDFNanomaterials (Basel)
February 2025
School of Materials Science and Engineering, Xi'an Key Laboratory of Textile Composites, Xi'an Polytechnic University, Xi'an 710048, China.
To enhance the electrocatalytic performance of a flexible Pd@CFs catalyst for methanol oxidation, deep cryogenic treatment in liquid nitrogen was introduced. The effects of the frequency and time of the deep cryogenic treatment on the surface crystal orientation, microstructure morphology, mechanical performance, and electrocatalytic performance for methanol oxidation were studied. The results showed that when the frequency of the deep cryogenic treatment was 2 times and the deep cryogenic time was 24 h, the electrocatalytic performance of the catalyst was the best.
View Article and Find Full Text PDFJ Cell Sci
March 2025
BRIC-National Centre for Cell Science, S.P. Pune University Campus, Ganeshkhind, Pune-411007, India.
P-bodies (PBs) and stress granules (SGs) are conserved, non-membranous cytoplasmic condensates of RNA-protein complexes. PBs are implicated in post-transcriptional regulation of gene expression through mRNA decay, translational repression and/or storage. Although much is known about the de novo formation of PBs and SGs involving liquid-liquid phase separation through multiple protein-protein and protein-RNA interactions, their subcellular localization and turnover mechanisms are less understood.
View Article and Find Full Text PDFHeliyon
February 2025
Brazilian Agricultural Research Corporation, Parque Estação Biológica, s/n, Av. Asa Norte, Brasília, CEP 70770-901, Brazil.
The lignin fraction of the lignocellulosic biomass corresponds to 15-30 % wt. This is largely obtained as a by-product of wood pulping to produce cellulose and paper, with the kraft process being the most used by industry. The chemical composition of lignin makes an excellent raw material for obtaining various chemical compounds with industrial applications, such as phenolic resins, biofuels and fine chemical products.
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