The use of solar energy to produce valuable chemicals has gained significant attention in recent years. In this area, photocatalytic hydrogen evolution and carbon dioxide reduction have become key focal points. Recently, amorphous cross-linked porous organic polymers (CPOPs) have emerged as promising photocatalysts due to their tunable band gaps, broad light absorption range, and high porosity. In this article, we highlight recent advancements in cutting-edge metal-free amorphous CPOPs for photocatalytic hydrogen evolution and carbon dioxide reduction. We examine the design principles, synthetic strategies, and structure-property relationships of various cross-linked porous polymers to achieve high photocatalytic performance. Additionally, we propose future research directions and offer insights to further advance CPOP-based photocatalysts for efficient solar-driven hydrogen evolution and carbon dioxide reduction.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/asia.202401368 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Quantum Well Superlattice Heteronanostructures for Efficient Photocatalytic Hydrogen Evolution.
ACS Nano
March 2025
State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China.
In this study, we construct a quantum well effect-based two-dimensional Z-scheme superlattice heteronanostructure photocatalyst constructed from hydrogen-bonded porphyrin organic frameworks (HOFs) and carbon nitride. Porphyrin HOFs extend spectral absorption, while their π-conjugation and electron density variations significantly enhance charge separation and exhibit favorable alignment with the energy levels of carbon nitride, thereby enabling efficient charge transfer. Carboxylic acid channels in the HOFs further promote the decomposition of water molecules, thereby boosting hydrogen production.
View Article and Find Full Text PDFEnhanced Hot/Free Electron Effect for Photocatalytic Hydrogen Evolution Based on 3D/2D Graphene/MXene Composite.
Small
March 2025
The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Photocatalytic hydrogen production through water splitting represents a promising strategy to store solar energy as chemical energy. Current photocatalysts primarily focus on traditional semiconductor materials, such as metal oxides, sulfides, nitrides, g-CN, etc. However, these materials often suffer from large bandgap and fast charge recombination, which limit sunlight utilization and result in unsatisfactory photon conversion efficiency.
View Article and Find Full Text PDFPicolinamide Functionalization on Carbon Nitride Edges for Enhanced Charge Separation and Photocatalytic Hydrogen Evolution.
Nanomaterials (Basel)
February 2025
College of Chemistry, Jilin University, Changchun 130012, China.
The periodical distribution of N and C atoms in carbon nitride (CN) not only results in localized electrons in each tri-s-triazine unit, but oxidation and reduction sites are in close contact spatially, resulting in severe carrier recombination. Herein, the hydrothermal method was first employed to synthesize carbon nitride (HCN), and then picolinamide (Pic) molecules were introduced at the edge of the carbon nitride so that the photo-generated electrons of the whole structure of the carbon nitride system were transferred from the center to the edge, which effectively promoted the separation of photo-generated carriers and inhibited the recombination of carriers in the structure. The introduced picolinamide not only changed the π-conjugated structure of the entire system but also acted as an electron-withdrawing group to promote charge transfer.
View Article and Find Full Text PDFPerovskite Type ABO Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects.
Chem Rev
March 2025
WA School of Mines: Minerals, Energy and Chemical Engineering (WASM-MECE), Curtin University, Perth, Western Australia 6102, Australia.
Since photocatalytic and electrocatalytic technologies are crucial for tackling the energy and environmental challenges, significant efforts have been put into exploring advanced catalysts. Among them, perovskite type ABO oxides show great promising catalytic activities because of their flexible physical and chemical properties. In this review, the fundamentals and recent progress in the synthesis of perovskite type ABO oxides are considered.
View Article and Find Full Text PDFCurrent status and advances in zinc anodes for rechargeable aqueous zinc-air batteries.
Sci Technol Adv Mater
January 2025
Materials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, Malaysia.
To promote sustainable development and reduce fossil fuel consumption, there is a growing demand for high-performance, cost-effective, safe and environmentally friendly batteries for large-scale energy storage systems. Among the emerging technologies, zinc-air batteries (ZABs) have attracted significant interest. By integrating the principles of traditional zinc-ion batteries and fuel cells, ZABs offer remarkably high theoretical energy density at lower production cost compared to the current state-of-the-art lithium-ion batteries (LIBs).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!