This work investigates the energy cane pyrolysis by process simulation in Aspen Plus, evaluating which variety maximizes bio-oil yield with further economics to evaluate process feasibility. Three cultivars were selected: two natural, and , and one, IACSP955000, generated by a breeding program. Firstly, 100 kg/h of wet biomass entered a stoichiometric reactor (RSTOIC) at 450 °C and 40 bar, generating biochar, bio-oil and gases. Secondly, a sensitivity analysis using CSTR determined its volume for an equivalent bio-oil yield. The economics involved two scenarios: 1) Two years payback and 10 years plant life; 2) 2.71 years payback and 20 years plant life. The produced the highest bio-oil yield. A 50 L CSTR produced bio-oil yield compared to the RSTOIC. The techno-economic results were: for the first scenario, bio-oil price of US$ 1.49/L and an internal rate of return (IRR) of 34 %; for the second, bio-oil price of US$ 1.15/L and an IRR of 16 %. The bio-oil price was 2.1 times higher than the international, suggesting either the employment of catalytic pyrolysis or energy integration to increase the bio-oil yield or to improve its quality.
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http://dx.doi.org/10.1016/j.heliyon.2025.e41642 | DOI Listing |
Heliyon
January 2025
School of Chemical Engineering, University of Campinas, Av. Albert Einstein 500, Campinas, SP, 13083-852, Brazil.
This work investigates the energy cane pyrolysis by process simulation in Aspen Plus, evaluating which variety maximizes bio-oil yield with further economics to evaluate process feasibility. Three cultivars were selected: two natural, and , and one, IACSP955000, generated by a breeding program. Firstly, 100 kg/h of wet biomass entered a stoichiometric reactor (RSTOIC) at 450 °C and 40 bar, generating biochar, bio-oil and gases.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria.
As global demand for fossil fuels rises amidst depleting reserves and environmental concerns, exploring sustainable and renewable energy sources has become imperative. This study investigated the pyrolysis of corncob, a widely available agricultural waste, using urea as a catalyst to enhance bio-oil production. The aim was to determine the optimum urea concentration and pyrolysis temperature for bio-oil yield from corncob.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Clean Energy Research Center, Korea Institute of Science and Technology (KIST), Hwarang-road 14-gil 5, Seongbuk-gu, Seoul 02792, Republic of Korea.
Electrocatalytic hydrodeoxygenation (EHDO) is a promising approach for upgrading biomass-derived bio-oils to sustainable fuels without the use of high-pressure hydrogen gas and elevated temperatures. However, direct EHDO for realistic hydrophobic lignin-based oil production remains challenging. Herein, we discuss the molecular dynamics that govern the EHDO of lignin bio-oil over Pt/C in an acidic electrolyte added with 2-propanol or a surfactant.
View Article and Find Full Text PDFRSC Adv
January 2025
School of Materials and Chemical Engineering, Chuzhou University Chuzhou Anhui 239000 China
This study successfully prepared La Ce CoO ( = 0.2, 0.4, 0.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781039, India.
The current investigation focuses on the copyrolysis of L. (a nonedible oilseed, also known as Nahar) and polyethyelene terephthalate (PET) plastic waste to gain insights into the composition of pyrolysates and the thermal decomposition of complex and mixed feedstocks. The physicochemical properties of the feedstocks were studied through thermogravimetric analysis at a heating rate of 15 °C min, bomb calorimetry, and proximate/ultimate analysis.
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