A combined experimental and theoretical study is carried out on the three-body recombination process in a gas of microwave-shielded polar molecules. For ground-state polar molecules dressed with a strong microwave field, field-linked bound states can appear in the intermolecular potential. We model three-body recombination into such bound states using classical trajectory calculations. Our results show that recombination can explain the enhanced loss rates observed at small microwave detunings in trapped samples of bosonic NaCs [Bigagli et al., Nat. Phys. 19, 1579-1584 (2023)NPAHAX1745-247310.1038/s41567-023-02200-6]. Specifically, our calculations reproduce the experimentally measured three-body loss rates across a wide range of microwave Rabi couplings, detunings, and temperatures. This work suggests that for bosonic shielded molecular systems in which the two-body loss is sufficiently suppressed and a field-linked bound state is present, the dominant loss process will be three-body recombination.
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http://dx.doi.org/10.1103/PhysRevLett.133.263402 | DOI Listing |
Phys Rev Lett
December 2024
Columbia University, Department of Physics, New York, New York, USA.
A combined experimental and theoretical study is carried out on the three-body recombination process in a gas of microwave-shielded polar molecules. For ground-state polar molecules dressed with a strong microwave field, field-linked bound states can appear in the intermolecular potential. We model three-body recombination into such bound states using classical trajectory calculations.
View Article and Find Full Text PDFJ Phys Chem A
November 2024
Dutch Institute for Fundamental Energy Research (DIFFER), Eindhoven 5600 MB, Eindhoven, The Netherlands.
The electrification of chemical processes using plasma generates an increasing demand for sensors, monitoring concentrations of plasma-activated species such as radicals. Radical probes are a low-cost in situ method for spatially resolved quantification of the radical density in a plasma afterglow using the heat from the exothermal recombination of radicals on a catalytic surface. However, distinguishing recombination heating from other heat fluxes in the system is challenging.
View Article and Find Full Text PDFMolecules
October 2024
Institute of Theoretical and Computational Chemistry, Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.
Three-body recombination reactions, in which two particles form a bound state while a third one bounces off after the collision, play significant roles in many fields, such as cold and ultracold chemistry, astrochemistry, atmospheric physics, and plasma physics. In this work, the dynamics of the recombination reaction for the N system over a wide temperature range (5000-20,000 K) are investigated in detail using the quasi-classical trajectory (QCT) method based on recently developed full-dimensional potential energy surfaces. The recombination products are N() + N() in the 1″ state, N() + N() in the 2″ state, and N() + N() in both the 1″ and 2″ states.
View Article and Find Full Text PDFJ Chem Phys
October 2024
Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
Inelastic n-changing collisions play an important role in the evolution of Rydberg atoms into ultracold plasmas. However, for the initially intermediate n (n ∼ 40) Rydberg states, these collisions can hardly be observed due to the low electron temperature in ultracold plasmas. In this work, we designed an experimental scheme to facilitate collisions between free electrons at 1.
View Article and Find Full Text PDFPhys Rev Lett
August 2024
Department of Quantum Science and Technology and Department of Fundamental and Theoretical Physics, Research School of Physics, Australian National University, Canberra 2600, Australia.
We investigate the fundamental viability of cooling ultracold atomic gases with quantum feedback control. Our Letter shows that the trade-off between the resolution and destructiveness of optical imaging techniques imposes constraints on the efficacy of feedback cooling, and that rapid rethermalization is necessary for cooling thermal gases. We construct a simple model to determine the limits to feedback cooling set by the visibility of density fluctuations, measurement-induced heating, and three-body atomic recombination.
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