To reduce greenhouse emissions and producing electricity with the smallest environmental impact, developing solar power technology is one of the most important milestones to achieve. Thus, to improve the efficiency of the concentrated solar power (CSP) plants, with lower environmental impact, is of great interest. This work reports the development of nanofluids, a colloidal suspension of nanomaterials in a fluid, based on an environment-friendly base fluid for improving the performance of the heat transfer process in CSP plants. The nanofluids contain Pt nanoparticles in a linear silicone-based heat transfer fluid, and their stability is guaranteed for several weeks. Their properties of interest, density, surface tension, viscosity, isobaric specific heat and thermal conductivity were characterized to determine the performance of the nanofluids in solar thermal technology. Improvements of about 6% and 24% in specific heat and thermal conductivity were found, without significant increases in viscosity. In addition, their effect on the performance of collectors and heat exchangers in CSP using these nanofluids was analysed, and an enhancement of about 40% is found. Specific heat enhancements are also discussed in view of the strength of the interactions between methyl siloxane groups and low Miller index surfaces of Pt, with data from density functional theory simulations.
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http://dx.doi.org/10.1038/s41598-024-84490-1 | DOI Listing |
Nat Mater
January 2025
School of Chemistry, Beihang University, Beijing, China.
The rational design of non-fullerene acceptors (NFAs) with both high crystallinity and photoluminescence quantum yield (PLQY) is of crucial importance for achieving high-efficiency and low-energy-loss organic solar cells (OSCs). However, increasing the crystallinity of an NFA tends to decrease its PLQY, which results in a high non-radiative energy loss in OSCs. Here we demonstrate that the crystallinity and PLQY of NFAs can be fine-tuned by asymmetrically adapting the branching position of alkyl chains on the thiophene unit of the L8-BO acceptor.
View Article and Find Full Text PDFSci Total Environ
January 2025
Program in Environmental and Polymer Engineering, Graduate School of INHA University, 100 Inha-ro, Michuhol-gu, Incheon 22212, Republic of Korea; Department of Environmental Engineering, INHA University, 100 Inha-ro, Michuhol-gu, Incheon 22212, Republic of Korea. Electronic address:
The increasing CO concentration in the atmosphere has substantial impacts on the global temperature. For energy sustainability and minimization of the effects of global warming, an approach to understand CO capturing and a carbon neutral culture is extremely essential in the present circumstances. The CO emission from vehicles and industries can be minimized using energy cost-effective techniques and can be converted more selectively into reusable fuels via thermochemical, electrochemical, photochemical, photocatalytic, electrocatalytic, biological and inorganic carbonate-based approaches.
View Article and Find Full Text PDFBioconjug Chem
January 2025
Department of Physics, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand, India.
Silica nano/microparticles have generated significant interest for the past decades, emerging as a versatile material with a wide range of applications in photonic crystals, bioimaging, chemical sensors, and catalysis. This study focused on synthesizing silica nano/microparticles ranging from 20 nm to 1.2 μm using the Stöber and modified Stöber methods.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China.
Asymmetric substitution is acknowledged as a straightforward yet potent approach for the optimization of small molecule acceptors (SMAs), thereby enhancing the power conversion efficiency (PCE) of organic solar cells (OSCs). In this work, we have successfully engineered and synthesized a novel asymmetric SMA, designated as Y6-R, which features a rhodanine-terminated inner side-chain. In devices with PM6 as the polymer donor, the asymmetric Y6-R demonstrated an impressive PCE of 18.
View Article and Find Full Text PDFLangmuir
January 2025
Key Laboratory of Thorium Energy, Chinese Academy of Science Shanghai Institute of Applied Physics, Shanghai 201800, China.
Hydrogen evolution from water, catalyzed by solar energy, is a promising yet challenging endeavor. Small-sized catalysts usually exhibit high utilization and high performance in the hydrogen evolution field. However, the high surface energy tends to make them aggregate.
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