A chitosan-based sensing membrane for on-site and sensitive dual-channel portable detection and efficient adsorption of Pb in groundwater.

Anal Chim Acta

State Key Laboratory of Applied Organic Chemistry and Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Gansu, Lanzhou, 730000, China. Electronic address:

Published: February 2025

The presence of lead ion (Pb) in groundwater poses a serious risk to human health, even at low levels. Therefore, it is essential to develop a new strategy for both selective detection and effective removal of Pb in groundwater, which has been rarely reported. Here, we developed a multi-functional chitosan-based fluorescent sensing membrane (CM-L/CG) by using a casting method for the sensitive/selective detection and removal of Pb in groundwater. The CM-L/CG membrane can be integrated into the portable laser-induced fluorescence spectrometer (LIFs) for on-site detection of Pb, with a low detection limit of 1.02 ppb. Moreover, the CM-L/CG membrane demonstrates an outstanding 99 % removal rate and an adsorption capacity of 247.6 mg g for Pb and the adsorption process is mainly controlled by chemisorption. Importantly, the CM-L/CG membrane enables the real-time and on-site detection of Pb in groundwater samples via a smartphone-based RGB (Red Green Blue) color analysis-assisted portable platform and portable LIFs-based platform, achieving acceptable results. This dual-functional fluorescent sensing membrane represents a breakthrough in environmental monitoring technology, offering a comprehensive solution for sensitive detection and efficient removal of Pb from groundwater.

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http://dx.doi.org/10.1016/j.aca.2025.343638DOI Listing

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