The removal of soot particles via high-performance catalysts is a critical area of research due to the growing concern regarding air pollution. Among various potential catalysts suitable for soot oxidation, cerium oxide-based materials have shown considerable promise. In this study, CeO samples obtained using a range of preparation methods (including hydrothermal synthesis (HT), sonochemical synthesis (SC), and hard template synthesis (TS)) were tested in soot combustion. They were compared to commercially available material (COM). All synthesized ceria catalysts were thoroughly characterized using XRD, RS, UV/Vis-DR, XPS, H-TPR, SEM, and TEM techniques. As confirmed in the current study, every tested ceria sample can be used as an effective soot oxidation catalyst, with a temperature of 50% soot conversion not exceeding 400 °C in a tight contact mode. A strong correlation was observed between the catalysts' Ce concentration and activity, with higher Ce levels leading to improved performance. These findings underscore the importance of synthesis in optimizing ceria-based catalysts for environmental applications.
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http://dx.doi.org/10.3390/molecules30020358 | DOI Listing |
Molecules
January 2025
Faculty of Chemistry, Jagiellonian University in Krakow, Gronostajowa 2, 30-387 Krakow, Poland.
The removal of soot particles via high-performance catalysts is a critical area of research due to the growing concern regarding air pollution. Among various potential catalysts suitable for soot oxidation, cerium oxide-based materials have shown considerable promise. In this study, CeO samples obtained using a range of preparation methods (including hydrothermal synthesis (HT), sonochemical synthesis (SC), and hard template synthesis (TS)) were tested in soot combustion.
View Article and Find Full Text PDFMolecules
January 2025
The Joint Graduate School of Energy and Environment, CHE Center for Energy Technology and Environment, King Mongkut's University of Technology Thonburi, 126 Pracha Uthit Rd., Bang Mod, Thung Khru, Bangkok 10140, Thailand.
A single-bed and dual-bed catalyst system was studied to maximize H production from the combination of partial oxidation of CH and water gas shift reaction. In addition, the different types of catalysts, including Ni, Cu, Ni-Re, and Cu-Re supported on gadolinium-doped ceria (GDC) were investigated under different operating conditions of temperature (400-650 °C). Over Ni-based catalysts, methane can easily dissociate on a Ni surface to give hydrogen and carbon species.
View Article and Find Full Text PDFMolecules
November 2024
Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181-UCCS-Unité de Catalyse et Chimie du Solide, F-59000 Lille, France.
The direct synthesis of dimethyl carbonate (DMC) from CO and methanol over ceria-based catalysts, in the presence of a dehydrating agent shifting the thermodynamical equilibrium of the reaction, has received significant interest recently. In this work, several dehydrating agents, such as molecular sieves, 2,2-dimethoxypropane (DMP), dimethoxymethane (DMM) and 1,1,1-trimethoxymethane (TMM), are combined with commercial ceria to compare their influence on the DMC yield obtained under the same set of operating conditions. TMM is found to be the most efficient; however, its conversion is not complete even after 48 h of reaction.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Key Laboratory for Colloid and Interface Chemistry, Key Laboratory of Special Aggregated Materials, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading the hydrogen generated from fossil or biomass sources by removing the residual CO. However, current industrial catalysts for this process, comprising Cu/ZnO and FeO-CrO, suffer from safety or environmental issues. In the past decades, ceria-based materials have attracted wide attention as WGS catalysts due to their abundant oxygen vacancies and tunable metal-support interaction.
View Article and Find Full Text PDFNano Lett
November 2024
Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
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