The phononic crystals composed of soft materials have received extensive attention owing to the extraordinary behavior when undergoing large deformations, making it possible to provide tunable band gaps actively. However, the inverse designs of them mainly rely on the gradient-driven or gradient-free optimization schemes, which require sensitivity analysis or cause time-consuming, lacking intelligence and flexibility. To this end, a deep learning-based framework composed of a conditional variational autoencoder and multilayer perceptron is proposed to discover the mapping relation from the band gaps to the topology layout applied with prestress. The nonlinear superelastic neo-Hookean model is employed to describe the constitutive characteristics, based on which the band structures are obtained via the transfer matrix method accompanied with Bloch theory. The results show that the proposed data-driven approach can efficiently and rapidly generate multiple candidates applied with predicted prestress. The band gaps are in accord with each other and also consistent with the prescribed targets, verifying the accuracy and flexibility simultaneously. Furthermore, based on the generalization performance, the design space is deeply exploited to obtain desired soft structures whose stop bands are characterized by wider bandwidth, lower location, and enhanced wave attenuation performance.
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Sci Rep
January 2025
Department of Physics, Khalifa University of Science and Technology, 127788, Abu Dhabi, United Arab Emirates.
In this study, biopolymer composites based on chitosan (CS) with enhanced optical properties were functionalized using Manganese metal complexes and black tea solution dyes. The results indicate that CS with Mn-complexes can produce polymer hybrids with high absorption, high refractive index and controlled optical band gaps, with a significant reduction from 6.24 eV to 1.
View Article and Find Full Text PDFSci Bull (Beijing)
January 2025
Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea; Department of Electrical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea; POSCO-POSTECH-RIST Convergence Research Center for Flat Optics and Metaphotonics, Pohang 37673, Republic of Korea. Electronic address:
Band topology has emerged as a novel tool for material design across various domains, including photonic and phononic systems, and metamaterials. A prominent model for band topology is the Su-Schrieffer-Heeger (SSH) chain, which reveals topological in-gap states within Bragg-type gaps (BG) formed by periodic modification. Apart from classical BGs, another mechanism for bandgap formation in metamaterials involves strong coupling between local resonances and propagating waves, resulting in a local resonance-induced bandgap (LRG).
View Article and Find Full Text PDFACS Nano
January 2025
Institute of Flexible Electronics, Xi'an Key Laboratory of Flexible Electronics, Northwestern Polytechnical University, Xi'an 710072, China.
Photoassisted lithium-sulfur (Li-S) batteries offer a promising approach to enhance the catalytic transformation kinetics of polysulfide. However, the development is greatly hindered by inadequate photo absorption and severe photoexcited carriers recombination. Herein, a photonic crystal sulfide heterojunction structure is designed as a bifunctional electrode scaffold for photoassisted Li-S batteries.
View Article and Find Full Text PDFMolecules
January 2025
School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China.
Isoindigo (IID)-based non-fullerene acceptors, known for their broad absorption spectra and high charge carrier mobilities, play a crucial role in organic photovoltaics. In this study, two A-DA'D-A type unfused ring acceptors (URAs), IDC8CP-IC and IDC6CP-IC, were designed and synthesized using cyclopentadithiophene (CPDT) and IID core units, each functionalized with different alkyl chains (2-hexyldecyl and 2-octyldodecyl), through an atom- and step-efficient direct C-H arylation (DACH) method. Both URAs, despite the absence of non-covalent conformation locking between CPDT and IID, demonstrated favorable molecular planarity, broad absorption ranges, low band gaps, and high molar absorption coefficients.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
School of Mechanical and Electrical Engineering, Hainan University, Haikou 570228, China.
The phononic crystals composed of soft materials have received extensive attention owing to the extraordinary behavior when undergoing large deformations, making it possible to provide tunable band gaps actively. However, the inverse designs of them mainly rely on the gradient-driven or gradient-free optimization schemes, which require sensitivity analysis or cause time-consuming, lacking intelligence and flexibility. To this end, a deep learning-based framework composed of a conditional variational autoencoder and multilayer perceptron is proposed to discover the mapping relation from the band gaps to the topology layout applied with prestress.
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