Arsenic (As) and antimony (Sb), with analogy structure, belong to VA group in the periodic table and pose a great public concern due to their potential carcinogenicity. The speciation distribution, migration and transformation, enrichment and retention, as well as bioavailability and toxicity of As and Sb are influenced by several environmental processes on mineral surfaces, including adsorption/desorption, coordination/precipitation, and oxidation/reduction. These interfacial reactions are influenced by the crystal facet of minerals with different atomic and electronic structures. This review starts with facets and examines As and Sb adsorption and transformation on mineral facets such hematite, titanium dioxide, and manganese dioxide. The main focus lies on three pressing issues that limit the understanding of the environmental fate of As and Sb: the facet-dependent intricacies of adsorption and transformation, the mechanisms underlying facet-dependent phenomena, and the impact of co-existing chemicals. We first discussed As and Sb adsorption behaviors, structures, and bonding chemistry on diverse mineral facets. Subsequently, the reactivity of various mineral facets was examined, with particular emphasis placed on their significance in the context of environmental catalysis for the oxidation of As(III) and Sb(III). Finally, the impact of co-existing cation, anion, or organic substances on the processes of adsorption and transport of As and Sb was reviewed. This comprehensive review enhances our understanding of the facet-dependent phenomena governing adsorption, transformation, and fate of contaminants. It underscores the critical role of mineral facets in dictating environmental reactions and paves the way for future research in this intriguing field.
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http://dx.doi.org/10.1016/j.jes.2024.01.016 | DOI Listing |
Molecules
January 2025
Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain.
Water pollution, resulting from industrial effluents, agricultural runoff, and pharmaceutical residues, poses serious threats to ecosystems and human health, highlighting the need for innovative approaches to effective remediation, particularly for non-biodegradable emerging pollutants. This research work explores the influence of shape-controlled nanocrystalline titanium dioxide (TiO NC), synthesized by a simple hydrothermal method, on the photodegradation efficiency of three different classes of emerging environmental pollutants: phenol, pesticides (methomyl), and drugs (sodium diclofenac). Experiments were conducted to assess the influence of the water matrix on treatment efficiency by using ultrapure water and stormwater (basic) collected from an urban drainage system as matrices.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address:
Arsenic (As) and antimony (Sb), with analogy structure, belong to VA group in the periodic table and pose a great public concern due to their potential carcinogenicity. The speciation distribution, migration and transformation, enrichment and retention, as well as bioavailability and toxicity of As and Sb are influenced by several environmental processes on mineral surfaces, including adsorption/desorption, coordination/precipitation, and oxidation/reduction. These interfacial reactions are influenced by the crystal facet of minerals with different atomic and electronic structures.
View Article and Find Full Text PDFJ Bone Miner Res
January 2025
McCaig Institute for Bone and Joint Health, Cumming School of Medicine, University of Calgary, Calgary AB, Canada.
Immune checkpoint inhibitors (ICI) are widely used in cancer treatment, yet their impact on bone health remains unclear. This study aimed to perform a retrospective cohort study utilizing routine computed tomography (CT) scans from patients with melanoma to perform opportunistic quantitative CT (QCT) analysis to investigate the effects of ICI treatment on skeletal health, including volumetric bone mineral density (vBMD) measurements and osteoarthritis (OA) parameters. A previously established machine-learning assisted opportunistic QCT pipeline was used to estimate lumbar spine vBMD from baseline and 12-month follow-up CT scans in patients with melanoma treated with ICI therapy and those not treated with ICI therapy.
View Article and Find Full Text PDFPurpose: This study aimed to elucidate the correlation between the degree of fat infiltration (FI) in thoracic paraspinal muscles and thoracic vertebral degeneration (TVD).
Methods: This cross-sectional study comprised 474 patients who underwent standard thoracic computed tomography (CT) scans. The FI was quantified as the percentage of adipose tissues within the cross-sectional area of thoracic paraspinal muscles.
J Environ Manage
January 2025
Chemistry Department, Faculty of Science, Benha University, Benha, 13518, Egypt.
The photocatalytic efficiency of TiO has been opposed by the fast recombination speed of photogenerated carriers. Here, g-CN -modified sulfate-built-in TiO quantum dots (ST-QDs) were successfully created using a simple ultrasonication-thermal procedure. g-CN-enrapped ST QDs with a 10 nm size were revealed by the characterization results.
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