A notable feature of systems with non-Hermitian skin effects is the sensitivity to boundary conditions. In this work, we introduce one type of boundary condition provided by a coupling impurity. We consider a system where a two-level system as an impurity couples to a nonreciprocal Su-Schrieffer-Heeger chain under periodic boundary conditions at two points with asymmetric couplings. We first study the spectrum of the system and find that asymmetric couplings lead to topological phase transitions. Meanwhile, a striking feature is that the coupling impurity can act as an effective boundary, and asymmetric couplings can also induce a flexibly adjusted zero mode. It is localized at one of the two effective boundaries or both of them by tuning coupling strengths. Moreover, we uncover three types of localization behaviors of eigenstates for this non-Hermitian impurity system with on-site disorder. These results corroborate the potential for control of a class of non-Hermitian systems with coupling impurities.
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http://dx.doi.org/10.3390/e27010078 | DOI Listing |
Talanta
January 2025
College of Pharmacy, Yanbian University, Park Road 977, Yanji, 133002, Jilin Province, PR China; Department of Chemistry, Interdisciplinary Program of Biological Functional Molecules, College of Integration Science, Yanbian University, Park Road 977, Yanji, 133002, Jilin Province, PR China. Electronic address:
B vitamins are essential for energy metabolism, nervous health, blood production, and the immune system. Their quantification in nutritional supplements and food is mandatory to manage a correct daily intake and dosage. In this study, a fast and sustainable method for the analysis of 8 B vitamins (VB, VB, VB, nicotinamide, VB, VB, VB, VB) in real samples using a 2D-carbon microfiber fractionation system combined with a triple quadrupole mass spectrometer (2DμCFs-QqQ-MS/MS) is presented.
View Article and Find Full Text PDFJ Am Soc Mass Spectrom
January 2025
MTA-ELTE Lendület (Momentum) Ion Mobility Mass Spectrometry Research Group, ELTE Eötvös Loránd University, Institute of Chemistry, Department of Analytical Chemistry, Pázmány Péter sétány 1/A, H-1117 Budapest, Hungary.
Cyclic ion mobility-mass spectrometry (cIM-MS) is a powerful technique for separating and identifying isomeric mixtures of compounds. When coupled with chromatography, cIM-MS creates a multidimensional separation system, with high resolving power and peak capacity. In this study, we report the cyclic ion mobility separation and high-resolution mass spectrometry identification of four regioisomers of a Sugammadex-related impurity, abbreviated as Di-OH-SGM.
View Article and Find Full Text PDFEntropy (Basel)
January 2025
School of Integrated Circuits, Tsinghua University, Beijing 100084, China.
A notable feature of systems with non-Hermitian skin effects is the sensitivity to boundary conditions. In this work, we introduce one type of boundary condition provided by a coupling impurity. We consider a system where a two-level system as an impurity couples to a nonreciprocal Su-Schrieffer-Heeger chain under periodic boundary conditions at two points with asymmetric couplings.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, National Industry-Education Integration Platform of Energy Storage, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China.
In situ polymerization strategies hold great promise for enhancing the physical interfacial stability in solid-state batteries, yet (electro)chemical degradation of polymerized interfaces, especially at high voltages, remains a critical challenge. Herein, we find interphase engineering is crucial for the polymerization process and polymer stability and pioneer an in situ polymerization-fluorination (Poly-FR) strategy to create durable interfaces with excellent physical and (electro)chemical stabilities, achieved by designing a bifunctional initiator for both polymerization and on-surface lithium donor reactions. The integrated in situ fluorination converts LiCO impurities on LiNiCoMnO (NCM811) surfaces into LiF-rich interphases, effectively inhibiting the aggressive (de)lithiation intermediates and protecting the interface from underlying chemical degradation, thereby surpassing the stability limitations of polymerization alone.
View Article and Find Full Text PDFBiotechnol Prog
January 2025
Purification Development, Genentech, South San Francisco, California, USA.
Platforms have long been implemented for downstream process development of monoclonal antibodies (mAbs) to streamline development and reduce timelines. These platforms are also increasingly being used for other complex biologics modalities. While development has traditionally been conducted at the lab bench scale in a sequential manner, automated miniaturized and parallelized approaches like RoboColumns and resin plates have also been implemented for chromatographic screening.
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