Pulsatile Ion Transport in Nanofiltration Membranes Coupled with Electrically Tunable Pore and Hydroxyl Electrostatic Interactions.

Pulsatile ion transport facilitates the adjusted transfer of substances, meeting the requirements for the gradient and timed separation of multiple components in membrane processes. Responsive nanofiltration membranes are thus currently receiving widespread attention but face limitations due to their narrow performance adjustment range. Herein, hydroxyl functional groups were introduced into electrically responsive nanofiltration membranes to broaden the adjustment range of separation performance through a combination of pore size sieving and functional group interactions, resulting in a greater change in rejection and flux compared to the original membrane. Membrane pore size is regulated by polypyrrole volume changes and becomes more variable when the cation's hydration radius is smaller. Although the hydroxyl group did not affect the charge transfer or volume change capacity of polypyrrole, it enhanced ion-pore interactions during ion transport, which was particularly pronounced in smaller nanochannels. The size effect of functional group interactions more strongly enhances the transmembrane energy barrier in the reduced state compared with the oxidized state, ultimately resulting in greater modulation of performance. This coupling strategy provides insights into the design of responsive membranes, offering the potential to achieve gradient separation of various solutes.