Photochemical mineralisation is an abiotic process by which the organic matter in natural waters, which is mostly dissolved, is eventually transformed into CO by the action of sunlight. The process has important implications for global C cycling, the penetration of sunlight into the water column, photochemical reactions, and microbial processes. Here we applied an approximated photochemical model to assess the extent of CO photogeneration by mineralisation of dissolved organic matter in lakes located between 60°S and 60°N latitude. The results suggest that, although lake-water organic matter would usually undergo faster photomineralisation in the tropical belt than elsewhere, by far the highest contributions to the photochemical production of CO would come from lakes located between 30°N and 60°N latitude. In particular, of the ~7 × 10 lakes we selected for the study, around 50 % of CO photogeneration would be accounted for by just 7 large lakes, of which only one is located in the tropical belt. It appears that the lake surface is a very important factor that affects the overall photomineralisation potential of dissolved organic matter.
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http://dx.doi.org/10.1016/j.scitotenv.2025.178512 | DOI Listing |
Environ Res
January 2025
Department of Environment Sciences and Engineering, The Gillings School of Global Public Health, University of North Carolina at Chapel Hill, 166 Rosenau, Campus Box # 7431, NC 27599, Chapel Hill, North Carolina, USA. Electronic address:
Greywater, originating from kitchen sinks and toilets, constitutes 75-80 % of the domestic wastewater produced in homes and can be reclaimed for non-potable uses. This study synthesized novel sludge-derived aluminosilicates and alginate-polyethyleneimine (PEI) biochar composites. The aluminosilicates offer a sustainable approach to sludge management, while alginate-polyethyleneimine presents a green biochar modification approach.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Institute of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, D-07743 Jena, Germany; Jena Center for Soft Matters (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, D-07743 Jena, Germany. Electronic address:
Nanomedicine, particularly gene delivery, holds immense potential and offers promising therapeutic options. Non-viral systems gained attention due to their binding capacity, stability and scalability. Among these, natural polysaccharides, such as pullulan, are advantageous in terms of sustainability, biocompatibility and potential degradability.
View Article and Find Full Text PDFJ Environ Manage
January 2025
College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, 266100, China.
This study employed in-situ online monitoring to assess the impact of Spartina alterniflora harvesting on greenhouse gas emissions. Their fluxes and δC values were measured in unvegetated tidal flat, low and medium vegetation coverage areas of the salt marsh wetlands along the south shore of Hangzhou Bay about a month after harvest. The objective was to clarify fluxes changes and interactions with environmental factors.
View Article and Find Full Text PDFJ Environ Manage
January 2025
School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an, 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an, 710055, China.
The complex pollution and nutrient-poor characteristics of surface waters result in the limited ability of conventional reactors to remove pollutants. In this study, a novel modified ceramsite material, modified with trivalent iron (Fe(III)) and fulvic acid (FA) to form ceramsite@Fe(III)@FA (HC), was used for the first time as a biocarrier to immobilize strain Cupriavidus sp. W12, constructing a biofilter to enhance nitrate (NO-N) removal in micro-polluted water.
View Article and Find Full Text PDFSci Total Environ
January 2025
Leibniz Institute for Baltic Sea Research Warnemünde (IOW), Rostock, Germany.
This study evaluates the distribution and sources of thermogenic organic matter in the Baltic Sea water column, focusing on polycyclic aromatic hydrocarbons (PAH), dissolved black carbon (DBC), and the imprint of thermogenic organic matter on the dissolved organic matter (DOM) pool. The spatial patterns and complex interactions between land-based and atmospheric sources were assessed from Kiel Bay to Pomeranian Bight within the water column with the combined targeted and untargeted approaches. The findings emphasize the significant influence of terrestrial inputs from the Oder River and autochthonous production composing DOM.
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