Exploring Moiré Superlattices and Memristive Switching in Non-van der Waals Twisted Bilayer BiOSe.

The discovery of moiré physics in two-dimensional (2D) materials has opened new avenues for exploring unique physical and chemical properties induced by intralayer/interlayer interactions. This study reports the experimental observation of moiré patterns in 2D bismuth oxyselenide (BiOSe) nanosheets grown through one-pot chemical reaction methods and a sonication-assisted layer separations technique. Our findings demonstrate that these moiré patterns result from the angular stacking of the nanosheets at various twist angles, leading to the formation of moiré superlattices (MSLs) with distinct periodicities. The presence of these superlattices was confirmed using transmission electron microscopy (TEM) images. The observation of moiré patterns in 2D BiOSe nanosheets highlights the potential of tuning the band structures of the non-van der Waals material and thus unlocking new material properties through precise control of intralayer/interlayer interactions. Furthermore, the stacked 2D BiOSe nanosheets show interesting memristive switching characteristics, presenting a promising candidate for artificial synapses and neuromorphic computing. Traditional memristors typically utilize a vertical metal-insulator-metal (MIM) structure, which relies on the formation of conductive filaments for resistive switching (RS). This configuration, however, often results in abrupt switching during various cycles and significant variation from device to device. Herein, defective BOSe moiré material exhibits a nonfilamentary RS switching characteristic in a two-terminal lateral device configuration. This design reveals an RS mechanism driven by the modulation of the Schottky barrier height (SBH) due to the movement of Se vacancies (V) under an external electric field. The fabricated device exhibits excellent RS behavior, achieving an RS ratio of ∼20 with a high degree of control and consistency across multiple cycles and from device to device. Interestingly, the device shows a stable negative differential resistance effect in the high-voltage region due to the carrier trapping process. Finally, we studied the stability of the MSL in BOSe through TEM imaging and electrical characterization on different device configurations to evaluate the repeatability of the switching characteristics.