Must excimers quench fluorescence? This study aims to clarify the misconception that excimers are defective species with weak fluorescence. For this purpose, we utilized a rigid xanthene template to connect anthracene units for constructing an inter-excimer and an intra-excimer. Their photophysical properties were systematically investigated in solution and crystal forms, representing dynamic and static environments, respectively. In solutions, the inter- and intra-excimers exhibited low fluorescence efficiencies due to the limited formation and ease of dissociation of the excimers. In crystals, the inter- and intra-excimers both demonstrated a significant increase in fluorescence efficiency, which was ascribed to the greatly suppressed non-radiation for the static excimer in a rigid environment. Furthermore, the efficiency of the inter-excimer was higher than that of the intra-excimer, which arose from the more stable excited state for more effective non-radiative suppression. Therefore, it was concluded that the probability and stability of excimer formation are the key factors for improving excimer fluorescence efficiency. Overall, their fluorescence efficiencies can be ranked as follows: dynamic inter-excimer < dynamic intra-excimer < static intra-excimer < static inter-excimer, which is subjected to environmental rigidity and excimer stability. This work will provide a comprehensive understanding of excimers and propose a novel design strategy to achieve high-efficiency fluorescent materials for innovative organic photo-functional applications.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11744815 | PMC |
http://dx.doi.org/10.1039/d4sc08001g | DOI Listing |
Chem Sci
January 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun 130012 China
Must excimers quench fluorescence? This study aims to clarify the misconception that excimers are defective species with weak fluorescence. For this purpose, we utilized a rigid xanthene template to connect anthracene units for constructing an inter-excimer and an intra-excimer. Their photophysical properties were systematically investigated in solution and crystal forms, representing dynamic and static environments, respectively.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi-110016, India.
Deep eutectic solvents (DESs) have emerged as solubilizing media of intense interest due partly to their easily tailorable physicochemical properties. Extensive H-bonding between the constituents in a two-constituent system is the major driving force for the formation of the DES. Addition of ethanolamine (MEA), a compound having H-bonding capabilities, to the DESs composed of a terpene [menthol (Men) or thymol (Thy)] and a fatty acid [-decanoic acid (DA)] results in an unprecedented increase in dynamic viscosity due to the extensive rearrangement in the H-bonding network and other interactions within the system, while the liquid mixture still behaves as a Newtonian fluid.
View Article and Find Full Text PDFAnal Bioanal Chem
January 2025
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China.
Chloramphenicol (CAP) is widely used in treating bacteria infection in animals and humans. However, the accumulation of CAP in food and environment caused serious health risk to human. Consequently, sensitive and selective detection of CAP is of great importance in environmental monitoring and food safety.
View Article and Find Full Text PDFSci Total Environ
January 2025
Department of Oncobiology and Epigenetics, Faculty of Biology and Environmental Protection, University of Lodz, Lodz, Poland; Laboratory of Transcriptional Regulation, Institute of Medical Biology PAS, Lodz, Poland. Electronic address:
Anal Chim Acta
January 2025
Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab, 140001, India. Electronic address:
Background: The unregulated use of pesticides by farmers, for crop productivity results in widespread contamination of organophosphates in real environmental samples, which is a growing societal concern about their potential health effects. The conventional approaches for the monitoring these organophosphate-based pesticides which include immunoassays, electrochemical methods, immunosensors, various chromatography techniques, along with some spectroscopic methods, are either costly, sophisticated, or involves the use of different metal complexes. Therefore, there is an urgent need for sensitive, quick, and easy-to-use detection techniques for the screening of widely used organophosphate-based pesticides.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!