Cobalt-based Photocatalysis: From Fundamental Principles to Applications in the Generation of C-X (X = C, O, N, H, Si) Bond.

Over the past few decades, the merger of photocatalysis and transition metal-based catalysis or self-photoexcitation of transition metals has emerged as a useful tool in organic transformations. In this context, cobalt-based systems have attracted significant attention as sustainable alternatives to the widely explored platinum group heavy metals (iridium, rhodium, ruthenium) for photocatalytic chemical transformations. This review encompasses the basic types of cobalt-based homogeneous photocatalytic systems, their working principles, and the recent developments (2018-2024) in C-X (X = C, N, O, H, Si) bond formations. Noteworthy to mention that cobalt-based heterogeneous photocatalysis is beyond the scope of the present review. An elaborate presentation on the mechanistic intricacies of cobalt-based photocatalysis, without any external photocatalyst, and cobalt-based dual organophotoredox catalysis have been provided in this comprehensive review, excluding the dual-metal photoredox catalysis. To the best of our knowledge, this is the only contemporary review encompassing the aforementioned two major types of cobalt-based photocatalysis, in general synthetic chemistry, covering all types of C-X bond formations spanning a range of the last six years.