In this project, a new heterogeneous polymeric ionic liquid catalyst based on vinylimidazole, stabilized on magnetic nanoparticles )FeO@AlO@[PBVIm]HSO) was prepared. Then the desired catalyst was identified by TGA, FT-IR, VSM, and TEM techniques. The efficiency of this catalyst was measured in the synthesis of chromene, xanthene, and dihydropyrimidinone. Moreover, the capability of the prepared sorbent for the extraction and determination of BPA (bisphenol A) was studied. Under the optimum conditions, the linearity range of the technique was between 0.5 and 100 µg L with the coefficient of determination (r) of 0.9948. Relative standard deviations for intra- and inter-day precision for the BPA (bisphenol A) at 20 µg L were in the range of 3.1-3.9% and 3.7-4.2%, respectively. The limit of detection and limit of quantification were 0.07 and 0.48 µg L respectively. Excellent efficiency, compatibility with environmental conditions, and easy recycling of the catalyst are among the most important features of the synthetic catalyst.
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http://dx.doi.org/10.1038/s41598-025-86751-z | DOI Listing |
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January 2025
Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), Shenzhen, Guangdong, 518055, China.
Polymeric mixed ionic-electronic conductors (PMIECs) are gaining significant attention due to their potential applications in organic electrochemical transistors (OECTs). However, the performance of n-type OECTs still lags behind that of their p-type counterparts. Here, the structure-performance correlation of fused bithiophene imide dimer (BTI2)-based PMIECs is systematically investigated with the backbone evaluation from acceptor-strong donor (A-SD) to acceptor-donor (A-D), to acceptor-weak donor (A-WD), to acceptor-weak acceptor (A-WA), and finally to A-A structures.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
Department of Chemistry, Indian Institute of Technology Bhilai, Durg, Chhattisgarh, 491002, India.
Utilization of reusable catalysts and reaction media has recently been an area of interest to devise a sustainable approach. Interestingly, photoinduced reversible deactivation radical polymerization (photoRDRP) of glycidyl methacrylate (GMA) is achieved with reusable and magnetically separable nano zero-valent Iron (nZVI). This resulted in well-defined poly(glycidyl methacrylate) (PGMA) (upto 22700 g mol) with a low dispersity (Đ ≤ 1.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China.
Janus graft copolymers, which combine the characteristics of block and graft copolymers, have been used in the fields of reaction catalysis, surface modification, and drug delivery, but their applications in lithium batteries have rarely been reported. Herein, Janus graft copolymers with polyethylene glycol (PEG) and polystyrene (PS) side chains are synthesized by combining reversible addition-fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) methods and doped with lithium salts to fabricate Janus bottlebrush polymer electrolytes (PEG-J-PS). The PEG side chains of the brush polymers impart good ion-conducting properties to the electrolytes, while the PS side chains improve the mechanical strength and thermal and chemical stability of the electrolytes.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran.
In this project, a new heterogeneous polymeric ionic liquid catalyst based on vinylimidazole, stabilized on magnetic nanoparticles )FeO@AlO@[PBVIm]HSO) was prepared. Then the desired catalyst was identified by TGA, FT-IR, VSM, and TEM techniques. The efficiency of this catalyst was measured in the synthesis of chromene, xanthene, and dihydropyrimidinone.
View Article and Find Full Text PDFFood Chem
January 2025
Department of Food Science and Technology, Faculty of Agriculture, Ferdowsi University of Mashhad, Azadi Sq., Mashhad, Khorasan Razavi P.O. Box 9177948944, Iran. Electronic address:
Protein fibrillation complex mechanisms led to an emerging trend in research for years. The mechanisms behind whey protein isolate (WPI) fibrillation driven by divalent cations remained still a matter of speculation. All cations (Ca, Fe, Mg, and Zn) enhanced the microenvironment polarity through π-π stacking, and the amide I and II shifts confirmed the fibrillation.
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