A novel helically twisted photonic crystal fiber (PCF) is designed and proposed for sensing toxic gases with refractive indices ranging from 1.00 to 1.08. The PCF consists of twelve hollow pipes arranged circularly around the hollow core to support THz radiation propagation. Low-loss polymer Topas is used as the background material of cladding. The fiber is twisted 360° over 50 cm to enhance anti-resonance in the THz region. The fundamental LP mode is analyzed using the finite-difference eigenmode (FDE) method. The sensor operates across four frequency bands (0.2 to 3.0 THz) with minimal transmission loss (~ 10⁻⁴ 1/cm). Key parameters such as refractive index sensitivity, relative sensitivity, resolution, and figure of merit (FOM) are evaluated. The average refractive index sensitivities are 1450, 2250, 3000, and 2550 for Bands 1 to 4, respectively, with 100% relative sensitivity across all bands. The sensor detects refractive index changes as small as 10⁻⁴. The FOM, defined as the inverse of the full width at half maximum, exceeds 30 1/RIU, reaching up to 250 1/RIU due to sharp resonance peaks. Compared to other THz sensors, this design offers enhanced performance in sensing gases like SOx, NOx, and CO, while maintaining a simple structure.
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http://dx.doi.org/10.1038/s41598-024-82704-0 | DOI Listing |
Sci Rep
January 2025
Department of Physics, Shiraz university of technology, Shiraz, Iran.
A novel helically twisted photonic crystal fiber (PCF) is designed and proposed for sensing toxic gases with refractive indices ranging from 1.00 to 1.08.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
RIKEN Center for Emergent Matter Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Some one-dimensional (1D) crystals containing a screw dislocation along their longer axis exhibit a helical twist due to lattice strain. These chiral structures have been thoroughly investigated by using transmission electron microscopy. However, whether two-dimensional (2D) crystals with a spiral surface pattern, presumably containing a screw dislocation, are structurally chiral remains unclear because their internal structures are not visible.
View Article and Find Full Text PDFChemistry
January 2025
Yamaguchi University, Department of Chemistry, 753-8512, Yamaguchi, JAPAN.
We report herein the synthesis of an unprecedented isomer of perylene, dicyclohepta[cd,fg]-as-indacene bearing two phenyl groups (1-Ph) by the nickel-mediated intramolecular homocoupling of a 4,4'-biazulene derivative (2). The X-ray crystallographic analysis and theoretical calculations revealed that 1-Ph adopts a unique helically twisted geometry although the local aromaticity of azulene moieties was preserved. The double covalent linkage of the two azulene skeletons imparts significant orbital interaction, which affords near-infrared (NIR) absorption (up to 1720 nm) and remarkable redox behaviors despite its closed-shell electronic structure.
View Article and Find Full Text PDFSmall
January 2025
Leicester Institute for Pharmaceutical Innovation, Leicester School of Pharmacy, De Montfort University, The Gateway, Leicester, LE1 9BH, UK.
Guiding molecular assembly of peptides into rationally engineered nanostructures remains a major hurdle against the development of functional peptide-based nanomaterials. Various non-covalent interactions come into play to drive the formation and stabilization of these assemblies, of which electrostatic interactions are key. Here, the atomistic mechanisms by which electrostatic interactions contribute toward controlling self-assembly and lateral association of ultrashort β-sheet forming peptides are deciphered.
View Article and Find Full Text PDFNat Commun
January 2025
Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, Chemical Biology Research Center, School of Pharmaceutical Sciences, Chongqing University, Chongqing, China.
Helicene-shaped molecules are compelling chemical structures with unique twisted helical chirality and remarkable properties. Although progress occurs in the catalytic asymmetric synthesis of helicene (-like) molecules, the enantioselective synthesis of multiple helicenes, especially four or higher helicity, is still challenging and has yet to be achieved. Herein, we report an organocatalytic [4 + 2] cycloadditions to achieve double S-shaped quadruple helicene-like molecules with high enantioselectivity (up to 96% e.
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