Hydrogen sulfide (HS), methanethiol (MeSH) and ethanethiol (EtSH) are volatile sulfur compounds (VSCs) produced during winemaking and are associated with negative 'reductive' aromas in wine. Anecdotal evidence suggests that oenological tannins may be used to remediate the 'reductive' character of wines, yet little scientific evidence or explanation supporting this observation has been published. In this study, it was found that the addition of oenological tannins significantly decreased HS, MeSH, and EtSH in model wine by up to 92 %, 90 % and 86 %, respectively, after two weeks of storage. Furthermore, the removal of HS from real wine matrices was accelerated at high pH levels. The reaction products of polyphenol oxidation and their ability to ameliorate the presence of MeSH and EtSH were studied in model systems and wines, and vescalagin/castalagin adducts of MeSH and EtSH were subsequently produced. This study provides evidence for the mechanism through which oenological tannins may diminish 'reductive' aromas in wine.
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http://dx.doi.org/10.1016/j.foodchem.2025.142777 | DOI Listing |
Food Chem
January 2025
Departamento de Horticultura, Facultad de Ciencias Agrarias, Universidad de Talca, 2 Norte 685, Talca, Chile.
Hydrogen sulfide (HS), methanethiol (MeSH) and ethanethiol (EtSH) are volatile sulfur compounds (VSCs) produced during winemaking and are associated with negative 'reductive' aromas in wine. Anecdotal evidence suggests that oenological tannins may be used to remediate the 'reductive' character of wines, yet little scientific evidence or explanation supporting this observation has been published. In this study, it was found that the addition of oenological tannins significantly decreased HS, MeSH, and EtSH in model wine by up to 92 %, 90 % and 86 %, respectively, after two weeks of storage.
View Article and Find Full Text PDFJ Sci Food Agric
February 2025
NEST, Istituto Nanoscienze - CNR and Scuola Normale Superiore, Pisa, Italy.
Background: Polyphenols are a group of compounds found in grapes, musts, and wines. Their levels are crucial for grape ripening, proper must fermentation, and final wine characteristics. Standard chemical analysis is commonly used to detect these compounds, but it is costly, time consuming, and requires specialized laboratories and operators.
View Article and Find Full Text PDFAntioxidants (Basel)
July 2023
Department of Agricultural, Food, Environmental, and Forestry Sciences and Technologies (DAGRI), University of Florence, Via Donizetti, 6, 50144 Florence, FI, Italy.
Twenty oenotannins from different botanical origins were studied in model wine solution (1 g/L, 12% ethanol, pH 3.5). An original device was created for measuring Oxidation-Reduction potential () of the solutions at 20 °C in strict anoxic condition by the electrochemical method of the platinum electrode zero-current potential.
View Article and Find Full Text PDFFoods
June 2023
University of Bordeaux, Bordeaux INP, INRAE, OENO, UMR 1366, ISVV, F-33140 Villenave d'Ornon, France.
J Sci Food Agric
September 2023
Università degli Studi di Torino, Dipartimento di Scienze Agrarie, Forestali e Alimentari, Alba, Italy.
Background: Sforzato di Valtellina (Sfursat) is a PDO reinforced red wine produced in Valtellina (northern Italy) from partially withered red grapes (Vitis vinifera L.) cv. Nebbiolo.
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