Functional Polyolefins and Composites.

Polyolefins are simple hydrocarbons that require additional chemical modifications or functional additives to give them custom functions. Recent research in the development of functional polyolefins has surpassed the traditional approach of simply improving surface properties by incorporating polar moieties. Creating custom functionalized polyolefins by using specific functional units has attracted increasing attention. This review summarizes advances in preparing custom functionalized polyolefin materials using functional units such as comonomers, chain-transfer agents, post-polymerization modification reagents, and functional fillers. Exploring new functional units and innovative synthetic strategies will further enhance the performance and expand the applications of functional polyolefins.