Core-shell In/H-Beta@Ce catalyst with enhanced sulfur and water tolerance for selective catalytic reduction of NO by CH.

J Hazard Mater

State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China. Electronic address:

Published: January 2025

A series of core-shell In/H-Beta@Ce catalysts were synthesized by encapsulating In/H-Beta within an amorphous CeO shell and then evaluated for the selective catalytic reduction of NO by CH (CH-SCR) under challenging conditions with SO and HO. IB@Ce-2 achieved 57.7 % NO conversion at 625°C, representing a 23.0 % improvement over In/H-Beta (35.0 %) under similar no-optimized conditions. Under optimized conditions, it further achieved 97.5 % NO conversion at 600°C. Durability tests for IB@Ce-2 under optimized conditions showed NO conversion decreased from 97.5 % to 52.7 % over three cycles, while long-term operation maintained over 70 % conversion for 60 minutes. The amorphous CeO shell enhanced SO and HO tolerance by shielding InO active sites, facilitating redox cycling, and limiting sulfate formation. These findings highlight IB@Ce-2 as a durable and efficient candidate for NO abatement in natural gas vehicles and other real-world applications.

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http://dx.doi.org/10.1016/j.jhazmat.2025.137204DOI Listing

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