Terminally fluorinated ether 5FDEE shows exceptional compatibility with LiPF, enabling high-performance Li-metal batteries. Li‖NMC811 cells with a 1 M LiPF in 5FDEE : FEC (9 : 1 v/v) electrolyte demonstrate remarkable cycling stability with an average coulombic efficiency exceeding 99.9% and no capacity fading over 550 cycles at 2.7-4.3 V Li/Li.

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http://dx.doi.org/10.1039/d4cc06265eDOI Listing

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