Recent transformations of vinylidene cyclopropanes (VDCPs).

Chem Commun (Camb)

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China.

Published: January 2025

Methodological studies on the transformations of vinylidene cyclopropanes (VDCPs) have been substantially developed in the past few decades, and significant progress has been achieved in visible light-mediated, non-metal-related, and transition metal-catalyzed processes. In particular, when reactive functional groups are introduced into the backbone of VDCPs, a variety of cascade or sequential transformations can take place to produce more complex cyclic or polycyclic compounds. This review describes the recent advancements in this field.

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http://dx.doi.org/10.1039/d4cc06137cDOI Listing

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