Solid waste is one of the primary contributors to environmental pollution currently, it is crucial to enhance the prevention and control of solid waste pollution in environmental management. The effectiveness of the second stage of purification in the industrial zinc hydrometallurgy is determined by the concentration of cobalt ion. Manual testing and monitoring of cobalt ion concentration are time consuming and costly, and prone to delays, which can result in discharge of cobalt ion concentration that does not meet the standards, leading to water pollution. Additionally, over-addition of zinc powder leads to a waste of resources, increasing the production cost of the company. Here, this work proposes a hybrid prediction model that combines the advantages of data decomposition and machine learning algorithms to predict the metal cobalt ion concentration in the effluent solution of a section of zinc hydrometallurgy refining purification in factory A. According to the different types of experiments, ablation experiments and contrast experiments are designed in this work under the same training and test data were used in the modeling process. Analytic and experimental results show that the proposed hybrid prediction model has the smallest error and the best fit between the actual and predicted values of cobalt ion concentration, and the appropriate graphs were finally selected for quantitative metrics analysis. The root mean square error was reduced by 4.2 %-73.9 %, the mean absolute error by 7.1 %-93.4 %, the mean percentage error by 7.7 %-86.7 % and the coefficient of determination by 1.3 %-134.6 %. The hybrid prediction model not only avoided the pollution of water resources by the cobalt ion concentration discharged in the purification, which is also of practical significance for the technicians to control the input quantity of zinc powder according to the prediction data in time and reduce the waste of resources.
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http://dx.doi.org/10.1016/j.scitotenv.2025.178420 | DOI Listing |
Sci Total Environ
January 2025
State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming, Yunnan 650093, PR China; Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, Yunnan 650093, PR China. Electronic address:
Solid waste is one of the primary contributors to environmental pollution currently, it is crucial to enhance the prevention and control of solid waste pollution in environmental management. The effectiveness of the second stage of purification in the industrial zinc hydrometallurgy is determined by the concentration of cobalt ion. Manual testing and monitoring of cobalt ion concentration are time consuming and costly, and prone to delays, which can result in discharge of cobalt ion concentration that does not meet the standards, leading to water pollution.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, 400076, India.
Stabilizing large easy-axis type magnetic anisotropy in molecular complexes is a challenging task, yet it is crucial for the development of information storage devices and applications in molecular spintronics. Achieving this requires a deep understanding of electronic structure and the relationships between structure and properties to develop magneto-structural correlations that are currently unexplored in the literature. Herein, a series of five-coordinate distorted square pyramidal Co complexes [Co(L)(X)].
View Article and Find Full Text PDFJ Biomed Mater Res A
January 2025
Advanced Ceramics, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan.
Implanted biomaterials release inorganic ions that trigger inflammatory responses, which recruit immune cells whose biochemical signals affect bone tissue regeneration. In this study, we evaluated how mouse macrophages (RAW264, RAW) and mesenchymal stem cells (KUSA-A1, MSCs) respond to seven types of ions (silicon, calcium, magnesium, zinc, strontium, copper, and cobalt) that reportedly stimulate cells related to bone formation. The collagen synthesis, alkaline phosphatase activity, and osteocalcin production of the MSCs varied by ion dose and type after culture in the secretome of RAW cells.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Department of Chemical Engineering, Zakir Hussain College of Engineering and Technology, Aligarh Muslim University, Aligarh, 202002, Uttar Pradesh, India.
Water pollution because of the presence of heavy metals remains a serious worry. The present work demonstrates the exclusion of cobalt ion (or Co(II)) from water using novel and cost-effective biosorbents. Initially, the biosorbent was chemically modified using orthophosphoric acid and then subjected to calcination to result acid modified date seed biochar (AMDB).
View Article and Find Full Text PDFSci Rep
January 2025
Department of Biology, Rasht Branch, Islamic Azad University, Rasht, Iran.
The current chemotherapy treatments for liver cancer have shown limited effectiveness. Therefore, there is an urgent need to develop new drugs to combat this disease more effectively. This study reports synthesis of cobalt oxide nanoparticles coated with glucose, and conjugated with Ellagic acid.
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