A nitrosyl complex of Mn-porphyrinate, 1 has been synthesized and characterized. It was found to donate a nitroxyl anion (NO) to suitable acceptors in dichloromethane solution in the presence of visible light. The evolution of NO and the characteristic reaction with PPh in the presence of H confirms the NO/HNO donation.
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| http://dx.doi.org/10.1039/d4cc06203e | DOI Listing |
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