The discovery of porous molecular solids has been constantly hindered by phase transformation and interpenetration. Here, we crystallize two molecules with three substituted carboxylic groups. A mesoporous, non-interpenetrated HOF that is constructed from 1,3,5-tri(4-carboxyphenyl)benzene (TCPB) is discovered and reported for the first time.
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| http://dx.doi.org/10.1039/d4cc06324d | DOI Listing |
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